tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate

Base Information

• Chemical Name: tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate
• CAS No.: 121079-94-5
• Molecular Formula: C₁₀H₁₄O₉
• Molecular Weight: 278.216
• Mol file: 121079-94-5.mol

Synonyms:tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate

Chemical Property of tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate

There total 1 articles about tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

malonic acid dimethyl ester (108-59-8) → Tetramethyl ethylenetetracarboxylate (1733-15-9) + tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate (121079-94-5)

Guidance literature:

With ammonium cerium(IV) nitrate; magnesium oxide; In acetonitrile; for 16h; Ambient temperature;

DOI:10.1080/00397919508011425

Reference yield: 98.0%

tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate (121079-94-5) → Tetramethyl ethylenetetracarboxylate (1733-15-9)

Guidance literature:

With methanesulfonyl chloride; triethylamine; In dichloromethane; at 0 ℃; for 2h;

DOI:10.1002/(SICI)1521-3773(20000303)39:5<902::AID-ANIE902>3.0.CO;2-5

Reference yield:

tetramethyl 1-hydroxyethane-1,1,2,2-tetracarboxylate (121079-94-5) + sulfuric acid (7664-93-9) → Tetramethyl ethylenetetracarboxylate (1733-15-9)

Guidance literature:

upstream raw materials:

malonic acid dimethyl ester

Downstream raw materials:

Tetramethyl ethylenetetracarboxylate

Refernces