3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

Base Information

Chemical Name:3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol
CAS No.:796883-88-0
Molecular Formula:C₅₁H₆₇O₉PSi₂
Molecular Weight:911.232
Hs Code.:

Synonyms:3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

Suppliers and Price of 3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

There total 1 articles about 3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 376590-85-1
1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

: 796883-88-0
3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 55 ℃; for 48h;
DOI:10.1021/ja0466098

Reference yield: 84.0%

: 100-51-6,185532-71-2
benzyl alcohol

: 796883-88-0
3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

: 796883-89-1
3,5-O-bis(t-butyldimethylsilyl)-1-O-dibenzylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

Guidance literature:: benzyl alcohol; With sodium hydride; In tetrahydrofuran;

3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol; In tetrahydrofuran; for 1h;
DOI:10.1021/ja0466098

Reference yield:

: 796883-88-0
3,5-O-bis(t-butyldimethylsilyl)-1-O-diphenylphosphate-2,4,6-tri-O-benzyl-D-myo-inositol

: C₂₅H₄₅O₁₆P₂^(3-)*3Na⁽¹⁺⁾

Guidance literature:: Multi-step reaction with 5 steps

1: 84 percent / NaH / tetrahydrofuran

2: 86 percent / HF*pyridine / tetrahydrofuran

3: 4,5-dicyanoimidazole / toluene; CH₂Cl₂

4: aq. H₂O₂ / toluene; CH₂Cl₂

5: 85 percent / H₂; NaHCO₃ / Pd(OH)2/C / 2-methyl-propan-2-ol; H₂O

With 4,5-dicyano-1H-imidazole; hydrogen; dihydrogen peroxide; sodium hydride; sodium hydrogencarbonate; pyridine hydrogenfluoride; palladium dihydroxide; In tetrahydrofuran; dichloromethane; water; toluene; tert-butyl alcohol;
DOI:10.1021/jo060702s