benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

Base Information

Chemical Name:benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside
CAS No.:133940-44-0
Molecular Formula:C₂₂H₂₆Cl₃NO₁₀
Molecular Weight:570.808
Hs Code.:

Synonyms:benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

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Chemical Property of benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

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Technology Process of benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

There total 13 articles about benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 220645-20-5
p-methylphenyl 3,4,6-tri-O-acetyl-2-deoxy-1-thio-2-(2,2,2-trichloroethyloxycarbonylamino)-β-D-glucopyranoside

: 100-51-6,185532-71-2
benzyl alcohol

: 133940-44-0,133940-45-1
benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: With N-iodo-succinimide; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere; Molecular sieve;
DOI:10.3987/COM-09-S(S)24

Reference yield: 94.0%

: 1384536-77-9
3,4,6-tri-O-acetyl-2-amino-2-deoxy-1-O,2-N-[(2,2,2-trichloroethoxy)methylylidene]-α-D-glucopyranose

: 100-51-6,185532-71-2
benzyl alcohol

: 133940-44-0,133940-45-1
benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: With sym-collidinium perchlorate; In dichloromethane; at 20 ℃; for 12h; Molecular sieve;
DOI:10.1016/j.carres.2012.03.026

Reference yield: 88.0%

: 187022-49-7
(2R,3S,4R,5R,6S)-2-(acetoxymethyl)-6-(phenylthio)-5-(((2,2,2-trichloroethoxy)carbonyl)amino)tetrahydro-2H-pyran-3,4-diyl diacetate

: 100-51-6,185532-71-2
benzyl alcohol

: 133940-44-0,133940-45-1
benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: (2R,3S,4R,5R,6S)-2-(acetoxymethyl)-6-(phenylthio)-5-(((2,2,2-trichloroethoxy)carbonyl)amino)tetrahydro-2H-pyran-3,4-diyl diacetate; benzyl alcohol; With N-iodo-succinimide; In dichloromethane; at -10 ℃; for 23h; Molecular sieve;

With trifluorormethanesulfonic acid; In dichloromethane;
DOI:10.1007/s10719-018-9839-2