1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene

Base Information

Chemical Name:1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene
CAS No.:108294-13-9
Molecular Formula:C₃₀H₄₆O₂Si₂
Molecular Weight:494.865
Hs Code.:

Synonyms:1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene

Suppliers and Price of 1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene

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Technology Process of 1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene

There total 4 articles about 1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 98582-27-5
2-[3-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyl]-ethanol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 108294-13-9
1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene

Guidance literature:: With 1H-imidazole; dmap; In dichloromethane; at 23 ℃; for 4h;
DOI:10.1021/jm00390a010

Reference yield:

: 930-68-7
cyclohexenone

: 108294-13-9
1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) CuI, 2.) N,N,N',N'-tetramethylethylenediamine (TMEDA), lutidine / 1.) THF, 50 deg C, 30 min, 2.) THF, from -60 deg C to 23 deg C, 5 h

2: 1.) 9-borabicyclo<3.3.1>nonane (9-BBN), 2.) aq. NaOH, H₂O₂ / 1.) THF, 23 deg C, 2.5 h, 2.) THF, ethanol, 50 deg C, 1 h

3: 98 percent / (dimethylamino)pyridine, imidazole / CH₂Cl₂ / 4 h / 23 °C

With 1H-imidazole; dmap; sodium hydroxide; copper(l) iodide; 9-borabicyclo[3.3.1]nonane dimer; N,N,N,N,-tetramethylethylenediamine; lutidine; dihydrogen peroxide; In dichloromethane;
DOI:10.1021/jm00390a010

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 108294-13-9
1-<(tert-butyldimethylsilyl)oxy>-3-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-1-cyclohexene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) CuI, 2.) N,N,N',N'-tetramethylethylenediamine (TMEDA), lutidine / 1.) THF, 50 deg C, 30 min, 2.) THF, from -60 deg C to 23 deg C, 5 h

2: 1.) 9-borabicyclo<3.3.1>nonane (9-BBN), 2.) aq. NaOH, H₂O₂ / 1.) THF, 23 deg C, 2.5 h, 2.) THF, ethanol, 50 deg C, 1 h

3: 98 percent / (dimethylamino)pyridine, imidazole / CH₂Cl₂ / 4 h / 23 °C

With 1H-imidazole; dmap; sodium hydroxide; copper(l) iodide; 9-borabicyclo[3.3.1]nonane dimer; N,N,N,N,-tetramethylethylenediamine; lutidine; dihydrogen peroxide; In dichloromethane;
DOI:10.1021/jm00390a010