Technology Process of dichlorobis((1-methylcyclohexyl)-η5-cyclopentadienyl)titanium
There total 1 articles about dichlorobis((1-methylcyclohexyl)-η5-cyclopentadienyl)titanium which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
HCl;
In
diethyl ether;
under Ar atm. to soln. cyclopenta-2,4-dienylidenecyclohexane in Et2O at 0°C soln. MeLi was added and stirred for 2 h, react. mixt. was added to soln. TiCl4 in Et2O and stirred for 2 h at 0°C and for 16 h at room temp.; react. was quenched with HCl, soln. was filtered through Celite, residuewas dissolved in CH2Cl2 and dried over MgSO4, volatiles were removed in vacuo; elem. anal.;
DOI:10.1021/om0342208
