[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]

Base Information

Chemical Name:[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]
CAS No.:738585-48-3
Molecular Formula:C₂₄H₁₈NiPS₃Se*C₃₆H₃₀NP₂
Molecular Weight:1110.81
Hs Code.:

[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C<sub>6</sub>H<sub>4</sub>S)2(o-C<sub>6</sub>H<sub>4</sub>SD))]

Synonyms:[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]

Suppliers and Price of [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]

Chemical Property:

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Technology Process of [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]

There total 2 articles about [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 738585-39-2
[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

: 7789-20-0
water-d2

: 738585-48-3
[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]

Guidance literature:: In tetrahydrofuran; acetonitrile; under N2; D2O (100 equiv.) added to MeCN-THF soln. of Ni complex at 5°C; stirred at 5°C for 10 min; layered with Et2O; sealed; crystd. at -15°C for 1 wk;
DOI:10.1021/ja048568l

Reference yield:

: 196961-63-4
[bis(triphenylphosphoranylidene)ammonium][Ni(CO)(SePh)3]

: 119327-19-4
tris(2-mercaptophenyl)phosphine

: 738585-48-3
[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]

Guidance literature:: Multi-step reaction with 2 steps

1: acetonitrile; tetrahydrofuran

2: acetonitrile; tetrahydrofuran

In tetrahydrofuran; acetonitrile;
DOI:10.1021/ja048568l

Reference yield:

: 738585-48-3
[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SD))]

: 738585-43-8
[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)3)]

Guidance literature:: With oxygen; In dichloromethane; byproducts: D2O; under N2; O2 purged through CH2Cl2 soln. of Ni complex at ambient temp.; not isolated; detd. by detd. by UV-vis and (2)H NMR spectra;
DOI:10.1021/ja048568l