[Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate)

Base Information

• Chemical Name: [Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate)
• CAS No.: 211561-56-7
• Molecular Formula: BF₄*C₃₃H₄₀N₂OPRu
• Molecular Weight: 699.542
• Mol file: 211561-56-7.mol

Synonyms:[Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate)

Chemical Property of [Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate)

There total 2 articles about [Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

NH-pyrazole (288-13-1) + [Ru(η(5)-C5H5)(=C=C=CPh2)(CO)(P(Pr(i))3)](tetrafluoroborate) (178325-73-0) → [Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate) (211561-56-7)

Guidance literature:

In dichloromethane; exclusion of air; 2 equivs. of pyrazole, stirring for 5 min at room temp.; evapn., washing (Et2O); elem. anal.;

DOI:10.1021/om980230a

Reference yield:

tetrafluoroboric acid diethyl ether (67969-82-8) + [Ru(η(5)-C5H5)(-C*C-CPh2-N2C3H3)(CO)(P(Pr(i))3)] (211561-57-8) → [Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate) (211561-56-7)

Guidance literature:

In dichloromethane; exclusion of air; 1 equiv. of Et2O*HBF4, room temp.;

DOI:10.1021/om980230a

Reference yield: 74.0%

[Ru(η(5)-C5H5)(-C=CH-CPh2-N2C3H3)(CO)(P(Pr(i))3)](tetrafluoroborate) (211561-56-7) → [Ru(η(5)-C5H5)(-C*C-CPh2-N2C3H3)(CO)(P(Pr(i))3)] (211561-57-8)

Guidance literature:

With NaOMe; In tetrahydrofuran; byproducts: NaBF4, MeOH; exclusion of air; 2 equivs. of NaOMe, stirring for 48 h at room temp.; evapn., addn. of MePh, filtration off of NaBF4, evapn., washing (MeOH); elem. anal.;

DOI:10.1021/om980230a

upstream raw materials:

NH-pyrazole

[Ru(η(5)-C5H5)(=C=C=CPh2)(CO)(P(Pr(i))3)](tetrafluoroborate)

tetrafluoroboric acid diethyl ether

[Ru(η(5)-C5H5)(-C*C-CPh2-N2C3H3)(CO)(P(Pr(i))3)]

Downstream raw materials:

[Ru(η(5)-C5H5)(-C*C-CPh2-N2C3H3)(CO)(P(Pr(i))3)]