(S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol

Base Information

Chemical Name:(S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol
CAS No.:459426-90-5
Molecular Formula:C₂₄H₃₂O₅
Molecular Weight:400.515
Hs Code.:

Synonyms:(S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol

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Chemical Property of (S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol

Chemical Property:

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Technology Process of (S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol

There total 11 articles about (S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 100-39-0
benzyl bromide

: 459426-89-2
(S)-2-Benzyloxy-1-((4R,5S)-5-hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol

: 459426-90-5
(S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 20 ℃;
DOI:10.1016/S0040-4039(02)00500-2

Reference yield: 95.0%

: 459426-96-1
2-Benzyloxy-1-((4S,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-one

: 459426-90-5
(S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol

Guidance literature:: With diisobutylaluminium hydride; In toluene; at 20 ℃;
DOI:10.1016/S0040-4039(02)00500-2

Reference yield:

: 1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7
methyl ribofuranoside

: 459426-90-5
(S)-2-Benzyloxy-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propan-1-ol

Guidance literature:: Multi-step reaction with 9 steps

1: H₂SO₄ / 0 - 20 °C

2: NaIO₄; RuO₂*H₂O / acetonitrile; CCl₄; H₂O

3: K₂CO₃ / dimethylformamide / 20 °C

4: 92 percent / diethyl ether / Heating

5: 92 percent / t-Bu₄NI; NaH / tetrahydrofuran / Heating

6: HCl / dioxane; H₂O / 60 °C

7: H₂SO₄ / 0 °C

8: 84 percent / LiAlH₄ / tetrahydrofuran / 0 °C

9: 98 percent / NaH / tetrahydrofuran / 20 °C

With hydrogenchloride; ruthenium(IV) oxide; sodium periodate; lithium aluminium tetrahydride; sulfuric acid; tetra(tert-butyl)ammonium iodide; sodium hydride; potassium carbonate; In tetrahydrofuran; 1,4-dioxane; tetrachloromethane; diethyl ether; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4039(02)00500-2