N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside

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Chemical Name:N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside
CAS No.:1319717-45-7
Molecular Formula:C₃₄H₅₀N₄O₇Si
Molecular Weight:654.879
Hs Code.:

Synonyms:N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside

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Chemical Property of N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside

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Technology Process of N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside

There total 1 articles about N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-2-deoxy-D-glucopyranoside

: 85272-31-7
di-tert-butylsilyl bis(trifluoromethanesulfonate)

: 1319717-45-7
N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside

Guidance literature:: In N,N-dimethyl-formamide; toluene; at -40 ℃; for 1.5h; Inert atmosphere;
DOI:10.1021/jo201179p

Reference yield: 98.0%

: 1319717-45-7
N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside

: 1319717-46-8
methyl (phenyl 4-O-[2,3,4-tri-O-benzyl-6-O-{9-fluorenylmethoxycarbonyl}-α-D-glucopyranosyl]-2,3-diazido-2,3-dideoxy-1-thio-β-D-mannopyranosyl uronate)

: 1319717-47-9
N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-(methyl 4-O-[2,3,4-tri-O-benzyl-6-O-{9-fluorenylmethoxycarbonyl}-α-D-glucopyranosyl]-2,3-diazido-2,3-dideoxy-β-D-mannopyranosyl uronate)-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside

Guidance literature:: methyl (phenyl 4-O-[2,3,4-tri-O-benzyl-6-O-{9-fluorenylmethoxycarbonyl}-α-D-glucopyranosyl]-2,3-diazido-2,3-dideoxy-1-thio-β-D-mannopyranosyl uronate); With 1,1'-sulfinylbisbenzene; In dichloromethane; toluene; at 20 ℃; for 0.333333h; Molecular sieve; Inert atmosphere; Large scale reaction;

With trifluoromethylsulfonic anhydride; In dichloromethane; toluene; at -80 - -60 ℃;

N-(benzyl)benzyloxycarbonyl-5-aminopentyl O-2-azido-4,6-O-di-tert-butylsilylidene-2-deoxy-α-D-glucopyranoside; In dichloromethane; toluene; at -80 - -10 ℃; for 4h; stereoselective reaction;
DOI:10.1021/jo201179p