3-Vinyl-7-oxabicyclo(4.1.0)hepta-2,4-diene

Base Information

Chemical Name:3-Vinyl-7-oxabicyclo(4.1.0)hepta-2,4-diene
CAS No.:78619-09-7
Molecular Formula:C8H8 O
Molecular Weight:120.151
Hs Code.:
DSSTox Substance ID:DTXSID80999908
Nikkaji Number:J65.675E
Mol file:78619-09-7.mol

Synonyms:1-vinylbenzene-3,4-oxide

Suppliers and Price of 3-Vinyl-7-oxabicyclo(4.1.0)hepta-2,4-diene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1-VINYLBENZENE-3,4-OXIDE 95.00%
5MG
$ 497.61

Total 3 raw suppliers

Chemical Property of 3-Vinyl-7-oxabicyclo(4.1.0)hepta-2,4-diene

Chemical Property:

Vapor Pressure:0.697mmHg at 25°C
Boiling Point:192°C at 760 mmHg
Flash Point:63.6°C
PSA：12.53000
Density:1.181g/cm³
LogP:1.43600
XLogP3:1.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:120.057514874
Heavy Atom Count:9
Complexity:201

Purity/Quality:: 1-VINYLBENZENE-3,4-OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CC1=CC2C(O2)C=C1

Technology Process of 3-Vinyl-7-oxabicyclo(4.1.0)hepta-2,4-diene

There total 3 articles about 3-Vinyl-7-oxabicyclo(4.1.0)hepta-2,4-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 81498-78-4
4,5-dibromo-4-(2-bromoethyl)cyclohexane-1,2-oxide

: 78619-09-7
1-vinylbenzene 3,4-oxide

Guidance literature:: With potassium tert-butylate; In diethyl ether; at -20 ℃; for 0.5h;
DOI:10.1016/S0040-4039(00)87055-0

Reference yield:

: 71647-37-5
1-(2'-hydroxyethyl)-1,4-cyclohexadiene

: 78619-09-7
1-vinylbenzene 3,4-oxide

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Br₂, 2.) PBr₃ / 1.) CCl₄, MeOH 2.) CCl₄, 0 deg C

2: perbenzoic acid / CHCl₃

3: 75 percent / potassium t-butoxide / diethyl ether / 0.5 h / -20 °C

With Perbenzoic acid; potassium tert-butylate; bromine; phosphorus tribromide; In diethyl ether; chloroform;
DOI:10.1016/S0040-4039(00)87055-0

Reference yield:

: 82296-88-6
4,5-dibromo-4-(2-bromoethyl)-1-cyclohexene

: 78619-09-7
1-vinylbenzene 3,4-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: perbenzoic acid / CHCl₃

2: 75 percent / potassium t-butoxide / diethyl ether / 0.5 h / -20 °C

With Perbenzoic acid; potassium tert-butylate; In diethyl ether; chloroform;
DOI:10.1016/S0040-4039(00)87055-0