di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate

Base Information

Chemical Name:di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate
CAS No.:604767-74-0
Molecular Formula:C₃₇H₄₉O₁₀P
Molecular Weight:684.764
Hs Code.:

Synonyms:di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate

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Chemical Property of di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate

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Technology Process of di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate

There total 7 articles about di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 16697-49-7
3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose

: 107-66-4
dibutyl phosphate

: 604767-74-0
di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate

Guidance literature:: With 4 A molecular sieve; In dichloromethane; at 20 ℃; for 0.366667h;
DOI:10.1021/ol0603155

Reference yield:

: 55628-54-1
3,4,6-tri-O-benzyl-D-glucal

: 108-24-7
acetic anhydride

: 107-66-4
dibutyl phosphate

: 604767-74-0
di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate

: 604767-71-7
di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl) phosphate

: di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-glucopyranosyl) phosphate

Guidance literature:: 3,4,6-tri-O-benzyl-D-glucal; dibutyl phosphate; With urea hydrogen peroxide adduct; methyltrioxorhenium(VII); In various solvent(s); at 20 ℃;

acetic anhydride; With pyridine; at 20 ℃; for 15h;
DOI:10.1016/S0040-4039(03)01386-8

Reference yield:

: 3254-16-8,4435-05-6,19189-54-9,29748-21-8,50801-29-1,64727-26-0,64727-27-1,65338-02-5,67672-68-8,78418-55-0,80877-03-8,103002-27-3,103002-29-5,132562-62-0
3,4,6-tri-O-acetyl-1,2-O-(1-methoxyethylidene)-β-D-mannopyranose

: 604767-74-0
di-n-butyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl) phosphate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium methylate / methanol / Inert atmosphere

2: sodium hydride / N,N-dimethyl-formamide / 0 - 25 °C / Inert atmosphere

3: triethylamine / dichloromethane / 0 - 25 °C / Molecular sieve; Inert atmosphere

With sodium methylate; sodium hydride; triethylamine; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/chem.202000496