C₆₃H₉₆Cl₂O₁₁Si₂

Base Information

Chemical Name:C₆₃H₉₆Cl₂O₁₁Si₂
CAS No.:392692-68-1
Molecular Formula:C₆₃H₉₆Cl₂O₁₁Si₂
Molecular Weight:1156.53
Hs Code.:

C<sub>63</sub>H<sub>96</sub>Cl<sub>2</sub>O<sub>11</sub>Si<sub>2</sub>

Synonyms:C₆₃H₉₆Cl₂O₁₁Si₂

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Chemical Property of C₆₃H₉₆Cl₂O₁₁Si₂

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Technology Process of C₆₃H₉₆Cl₂O₁₁Si₂

There total 59 articles about C₆₃H₉₆Cl₂O₁₁Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 75-11-6
diiodomethane

: 392692-67-0
C₆₂H₉₄Cl₂O₁₂Si₂

: 392692-68-1
C₆₃H₉₆Cl₂O₁₁Si₂

Guidance literature:: diiodomethane; With chloro-trimethyl-silane; lead(II) iodide; zinc; In tetrahydrofuran; at 20 ℃; for 0.5h;

With titanium tetrachloride; In tetrahydrofuran; dichloromethane; at 20 ℃; for 1h;

C₆₂H₉₄Cl₂O₁₂Si₂; In tetrahydrofuran; dichloromethane; at 20 ℃; for 4h;
DOI:10.1039/b504149j

Reference yield:

: 862509-84-0
(4R,5R,6R)-5-benzyloxy-4-[1-hydroxy-prop-2-(R)-yl]-2,2,6-trimethyl-1,3-dioxane

: 392692-68-1
C₆₃H₉₆Cl₂O₁₁Si₂

Guidance literature:: Multi-step reaction with 18 steps

1.1: Dess-Martin periodinane / CH₂Cl₂ / 3 h / 20 °C

2.1: LiCl; i-PrNEt₂ / acetonitrile / 16 h / 20 °C

3.1: enriched AD-mix-β; MeSO3NH2 / 2-methyl-propan-2-ol; H2O / 8 h / 20 °C

4.1: H₂; NaHCO₃ / Pd(OH)2/C / methanol / 20 h / 20 °C

5.1: Ph₃CBF₄ / tetrahydrofuran / 2 h / 0 °C

6.1: DIBAL-H / CH₂Cl₂ / 0.5 h / -78 °C

6.2: Ba(OH)2 / tetrahydrofuran; H₂O / 16 h / 20 °C

7.1: AcOH / tetrahydrofuran; H₂O / 48 h / 20 °C

7.2: 86 percent / KOH / methanol / 24 h / 20 °C

8.1: toluene / 2 h / 120 °C

9.1: tetrapropylammonium perruthenate; N-methylmorpholine N-oxide / CH₂Cl₂ / 0.5 h / 20 °C

10.1: Et₃N / diethyl ether / 2.5 h / -78 °C

11.1: diethyl ether / 16 h / -78 - -20 °C

11.2: H₂O₂ / methanol; H₂O / 2 h / 0 - 20 °C / pH 7

12.1: PPTS / methanol / 1 h / 20 °C

13.1: imidazole; Et₃N / dimethylformamide / 16 h / 20 °C

14.1: OsO₄; H₂O; Me₃NO / acetone / 16 h / 20 °C

14.2: Pb(OAc)4; Na₂CO₃ / CH₂Cl₂ / 0.67 h / 0 °C

15.1: Et₃N / diethyl ether / 1.5 h / -78 - -40 °C

16.1: diethyl ether / 16 h / -78 °C

16.2: H₂O₂ / methanol; H₂O / 2.5 h / 0 °C / pH 7

17.1: 93 percent / imidazole / dimethylformamide / 3 h / 20 °C

18.1: Zn; TiCl₄; PbI₂ / tetrahydrofuran; CH₂Cl₂ / 4 h / 20 °C

With 1H-imidazole; osmium(VIII) oxide; tetrapropylammonium perruthennate; sulfamic acid methyl ester; N,N-diethyl-N-isopropylamine; trimethylamine-N-oxide; enriched AD-mix-β; water; hydrogen; trityl tetrafluoroborate; pyridinium p-toluenesulfonate; titanium tetrachloride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; 4-methylmorpholine N-oxide; triethylamine; lithium chloride; lead(II) iodide; zinc; palladium dihydroxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; tert-butyl alcohol; 1.1: Dess-Martin oxidation / 2.1: Horner-Wadsworth-Emmons olefination / 3.1: Sharpless dihydroxylation / 6.2: Horner-Wadsworth-Emmons olefination / 7.1: hetero-Michael cyclization / 8.1: Petasis methylenation;
DOI:10.1002/1521-3773(20011105)40:21<4055::AID-ANIE4055>3.0.CO;2-H

Reference yield:

: 194934-58-2
(S)-2-[5-(R)-benzyloxy-2,2,6-(6R)-trimethyl-1,3-dioxan-4-(R)-yl]-propionaldehyde

: 392692-68-1
C₆₃H₉₆Cl₂O₁₁Si₂

Guidance literature:: Multi-step reaction with 17 steps

1.1: LiCl; i-PrNEt₂ / acetonitrile / 16 h / 20 °C

2.1: enriched AD-mix-β; MeSO3NH2 / 2-methyl-propan-2-ol; H2O / 8 h / 20 °C

3.1: H₂; NaHCO₃ / Pd(OH)2/C / methanol / 20 h / 20 °C

4.1: Ph₃CBF₄ / tetrahydrofuran / 2 h / 0 °C

5.1: DIBAL-H / CH₂Cl₂ / 0.5 h / -78 °C

5.2: Ba(OH)2 / tetrahydrofuran; H₂O / 16 h / 20 °C

6.1: AcOH / tetrahydrofuran; H₂O / 48 h / 20 °C

6.2: 86 percent / KOH / methanol / 24 h / 20 °C

7.1: toluene / 2 h / 120 °C

8.1: tetrapropylammonium perruthenate; N-methylmorpholine N-oxide / CH₂Cl₂ / 0.5 h / 20 °C

9.1: Et₃N / diethyl ether / 2.5 h / -78 °C

10.1: diethyl ether / 16 h / -78 - -20 °C

10.2: H₂O₂ / methanol; H₂O / 2 h / 0 - 20 °C / pH 7

11.1: PPTS / methanol / 1 h / 20 °C

12.1: imidazole; Et₃N / dimethylformamide / 16 h / 20 °C

13.1: OsO₄; H₂O; Me₃NO / acetone / 16 h / 20 °C

13.2: Pb(OAc)4; Na₂CO₃ / CH₂Cl₂ / 0.67 h / 0 °C

14.1: Et₃N / diethyl ether / 1.5 h / -78 - -40 °C

15.1: diethyl ether / 16 h / -78 °C

15.2: H₂O₂ / methanol; H₂O / 2.5 h / 0 °C / pH 7

16.1: 93 percent / imidazole / dimethylformamide / 3 h / 20 °C

17.1: Zn; TiCl₄; PbI₂ / tetrahydrofuran; CH₂Cl₂ / 4 h / 20 °C

With 1H-imidazole; osmium(VIII) oxide; tetrapropylammonium perruthennate; sulfamic acid methyl ester; N,N-diethyl-N-isopropylamine; trimethylamine-N-oxide; enriched AD-mix-β; water; hydrogen; trityl tetrafluoroborate; pyridinium p-toluenesulfonate; titanium tetrachloride; diisobutylaluminium hydride; sodium hydrogencarbonate; acetic acid; 4-methylmorpholine N-oxide; triethylamine; lithium chloride; lead(II) iodide; zinc; palladium dihydroxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; tert-butyl alcohol; 1.1: Horner-Wadsworth-Emmons olefination / 2.1: Sharpless dihydroxylation / 5.2: Horner-Wadsworth-Emmons olefination / 6.1: hetero-Michael cyclization / 7.1: Petasis methylenation;
DOI:10.1002/1521-3773(20011105)40:21<4055::AID-ANIE4055>3.0.CO;2-H