(Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal

Base Information

Chemical Name:(Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal
CAS No.:912967-58-9
Molecular Formula:C₂₇H₄₀O₃Si₂
Molecular Weight:468.784
Hs Code.:

Synonyms:(Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal

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Technology Process of (Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal

There total 5 articles about (Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 912967-50-1
(Z)-ethyl 4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butyrate

: 912967-58-9
(Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 1.5h;
DOI:10.1021/ol061957v

Reference yield:

: 912967-75-0
4-trimethylsilanyl-but-2-ynyl 2,2,2-trichloroacetimidate

: 912967-58-9
(Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal

Guidance literature:: Multi-step reaction with 3 steps

1: 61 percent / trimethylsilyl trifluoromethanesulfonate; 2,4,6-tri-tert-butylpyrimidine / cyclohexane / 5 h / 20 - 25 °C

2: 89 percent / Raney nickel; H₂ / ethanol / 0.2 h / 20 - 25 °C

3: 87 percent / DIBALH / CH₂Cl₂; toluene / 1.5 h / -78 °C

With trimethylsilyl trifluoromethanesulfonate; hydrogen; nickel; diisobutylaluminium hydride; 2,4,6-tri-tert-butylpyrimidine; In ethanol; dichloromethane; cyclohexane; toluene;
DOI:10.1021/ol061957v

Reference yield:

: 912967-40-9
ethyl 4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-ynyloxy)butyrate

: 912967-58-9
(Z)-4-(tert-butyl-diphenyl-silanyloxy)-3-(4-trimethylsilanyl-but-2-enyloxy)butanal

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / Raney nickel; H₂ / ethanol / 0.2 h / 20 - 25 °C

2: 87 percent / DIBALH / CH₂Cl₂; toluene / 1.5 h / -78 °C

With hydrogen; nickel; diisobutylaluminium hydride; In ethanol; dichloromethane; toluene;
DOI:10.1021/ol061957v