para-methylbenzylbis(dimethylglyoximato)(pyridine)cobalt(III)

Base Information

Chemical Name:para-methylbenzylbis(dimethylglyoximato)(pyridine)cobalt(III)
CAS No.:36583-14-9
Molecular Formula:C₂₁H₂₈CoN₅O₄
Molecular Weight:473.478
Hs Code.:

Synonyms:para-methylbenzylbis(dimethylglyoximato)(pyridine)cobalt(III)

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Chemical Property of para-methylbenzylbis(dimethylglyoximato)(pyridine)cobalt(III)

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Technology Process of para-methylbenzylbis(dimethylglyoximato)(pyridine)cobalt(III)

There total 1 articles about para-methylbenzylbis(dimethylglyoximato)(pyridine)cobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 623-24-5
1,4-bis(bromomethyl)benzene

: chloropyridinecobaloxime(III)

: 36583-14-9
para-methylbenzylbis(dimethylglyoximato)(pyridine)cobalt(III)

: [Co(pyridine)(dimethyl glyoxime)2(p-CH₂C₆H₄CH₂Cl)]

: [(Co(pyridine)(dimethyl glyoxime)2)2(p-xylylene)]

Guidance literature:: With aq. NaOH; NaBH₄; In methanol; diethyl ether; water; aq. NaOH was added to suspn. of Co complex in methanol; mixt. was purgedwith Ar for 0.5 h; aq. soln. of NaBH4 was added; cooled to 0°C; Ar-purged soln. of dihalide in Et2O was added dropwise; mixt. was stirre d in dark for 5 h; mixt. poured into ice-cold H2O containing few drops of pyridine; filtered; washed (water); dried over P2O5 in dark; dissolved in CHCl3; chromd. (silica gel, ethyl acetate/CHCl3, (80/20); ethyl acetate; ethyl acetate/methanol (90/10)); elem. anal.;
DOI:10.1021/om034273p