{((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}⁽¹⁺⁾*SO₃CF₃^(1-)={((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}SO₃CF₃

Base Information

• Chemical Name: {((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}⁽¹⁺⁾*SO₃CF₃^(1-)={((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}SO₃CF₃
• CAS No.: 139168-14-2
• Molecular Formula: CF₃O₃S*C₃₀H₃₂NP₂Pd
• Molecular Weight: 724.029

Synonyms:{((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}⁽¹⁺⁾*SO₃CF₃^(1-)={((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}SO₃CF₃

Chemical Property of {((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}⁽¹⁺⁾*SO₃CF₃^(1-)={((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}SO₃CF₃

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Technology Process of {((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}⁽¹⁺⁾*SO₃CF₃^(1-)={((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}SO₃CF₃

There total 1 articles about {((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}⁽¹⁺⁾*SO₃CF₃^(1-)={((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(CH₃)(CH₃CN)}SO₃CF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

[PdCl(CH3)(bis(diphenylphosphino)propane)] (139168-06-2) + silver trifluoromethanesulfonate (2923-28-6) → {((C6H5)2PCH2CH2CH2P(C6H5)2)Pd(CH3)(CH3CN)}(1+)*SO3CF3(1-)={((C6H5)2PCH2CH2CH2P(C6H5)2)Pd(CH3)(CH3CN)}SO3CF3 (139168-14-2)

Guidance literature:

With acetonitrile; In dichloromethane; acetonitrile; byproducts: AgCl; dropwise addn. of AgSO3CF3 in CH3CN to a rapidly stirred soln. of the Pd complex in CH2Cl2/CH3CN (under N2); filtered, filtrate collected in Et2O (-20°C, rapid stirring), ppt. filtered off, washed (benzene, pentane), recrystd. (CH2Cl2/ Et2O); elem. anal.;

DOI:10.1021/om00040a034

Reference yield:

{((C6H5)2PCH2CH2CH2P(C6H5)2)Pd(CH3)(CH3CN)}(1+)*SO3CF3(1-)={((C6H5)2PCH2CH2CH2P(C6H5)2)Pd(CH3)(CH3CN)}SO3CF3 (139168-14-2) → {((C6H5)2PCH2CH2CH2P(C6H5)2)Pd(C(O)CH3)(CH3CN)}(1+)*CF3SO3(1-)={((C6H5)2PCH2CH2CH2P(C6H5)2)Pd(C(O)CH3)(CH3CN)}CF3SO3 (139168-21-1)

Guidance literature:

With carbon monoxide; In dichloromethane-d2; High Pressure; Pd complex dissolved in CD2Cl2 (under N2, high-pressure NMR tube), 25 bar of CO applied (235 K); not isolated; (1)H- and (31)P-NMR; Kinetics;

DOI:10.1021/om00040a034

Reference yield:

{((C6H5)2PCH2CH2CH2P(C6H5)2)Pd(CH3)(CH3CN)}(1+)*SO3CF3(1-)={((C6H5)2PCH2CH2CH2P(C6H5)2)Pd(CH3)(CH3CN)}SO3CF3 (139168-14-2) → [(1,3-bis(diphenylphosphanyl)propane)palladium(II)(CH3)triflate] (284497-49-0)

Guidance literature:

In dichloromethane; byproducts: CH3CN; placing a droplet of ((1,3-bis(diphenylphosphanyl)propane)Pd(CH3)(CH3CN))OSO2CF3 onto gold-coated silicon wafer; drying; IR;

DOI:10.1002/(SICI)1521-3773(20000515)39:10<1848::AID-ANIE1848>3.0.CO;2-8

upstream raw materials:

[PdCl(CH₃)(bis(diphenylphosphino)propane)]

silver trifluoromethanesulfonate

Downstream raw materials:

{((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(C(O)CH₃)(CH₃CN)}⁽¹⁺⁾*CF₃SO₃^(1-)={((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)Pd(C(O)CH₃)(CH₃CN)}CF₃SO₃

[(1,3-bis(diphenylphosphanyl)propane)palladium(II)(CH₃)triflate]

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