(E)-methyl 3-(1H-naphtho-[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenyl acrylate

Base Information

Chemical Name:(E)-methyl 3-(1H-naphtho-[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenyl acrylate
CAS No.:1393880-51-7
Molecular Formula:C₂₀H₁₇BN₂O₂
Molecular Weight:328.178
Hs Code.:

Synonyms:(E)-methyl 3-(1H-naphtho-[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenyl acrylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-methyl 3-(1H-naphtho-[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenyl acrylate

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Technology Process of (E)-methyl 3-(1H-naphtho-[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenyl acrylate

There total 1 articles about (E)-methyl 3-(1H-naphtho-[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 108-86-1,52753-63-6
bromobenzene

: CH₃OCOCHCHB(NHC₁₀H₆NH)

: 1393880-51-7
(E)-methyl 3-(1H-naphtho-[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenyl acrylate

Guidance literature:: With tetra(n-butyl)ammonium hydrogensulfate; palladium diacetate; triethylamine; triphenylphosphine; In acetonitrile; at 80 ℃; for 10h; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ol301958x

Reference yield:

: 1393880-51-7
(E)-methyl 3-(1H-naphtho-[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenyl acrylate

: 1393880-59-5
methyl (R)-3-(1H-naphtho[1,8-de][1,3,2]-diazaborinin-2(3H)-yl)-3-phenylpropanoate

: 1393880-59-5
(S)-methyl 3-(1H-naphtho[1,8-de][1,3,2]diazaborinin-2(3H)-yl)-3-phenylpropanoate

Guidance literature:: With (R)-tol-BINAP; copper(l) chloride; sodium t-butanolate; In toluene; at 20 ℃; for 0.333333h; Overall yield = 88 %; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol301958x