dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside

Base Information

Chemical Name:dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside
CAS No.:174077-02-2
Molecular Formula:C₂₈H₄₁N₃O₅Si
Molecular Weight:527.736
Hs Code.:

Synonyms:dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside

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Chemical Property of dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside

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Technology Process of dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside

There total 10 articles about dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 174077-01-1
Thexyldimethylsilyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 174077-02-2
dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside

Guidance literature:: With hydrogenchloride; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether;

Reference yield: 85.0%

: thexyldimethylsilyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 174077-02-2
dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside

Guidance literature:: thexyldimethylsilyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside; With triethylsilane; In dichloromethane; for 0.5h;

With trifluoroacetic acid; In dichloromethane; at 0 - 20 ℃; regioselective reaction;
DOI:10.3998/ark.5550190.0014.214

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 174077-02-2
dimethylthexylsilyl 3,6-di-O-benzyl-2-deoxy-2-azido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / p-TsOH / acetonitrile / 1 h

2: 93 percent / NaH / dimethylformamide / 2 h / -15 °C

3: 86 percent / NaCNBH₃, HCl / diethyl ether; tetrahydrofuran

With hydrogenchloride; sodium hydride; sodium cyanoborohydride; toluene-4-sulfonic acid; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; acetonitrile;