1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol

Base Information

Chemical Name:1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol
CAS No.:110372-64-0
Molecular Formula:C₃₆H₄₈O₄SSi
Molecular Weight:604.926
Hs Code.:

Synonyms:1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol

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Chemical Property of 1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol

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Technology Process of 1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol

There total 3 articles about 1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 110372-63-9
1D-(1,2,4,5S/3,5C)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldimethylsiloxy)methyl>-5-C-(ethylthio)-1,2,3,4-cyclohexantetrol

: 110372-64-0
1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol

Guidance literature:: With 3 A molecular sieve; triphenylphosphine; diethylazodicarboxylate; molecular sieve; In toluene; for 14h; Ambient temperature;

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 110372-64-0
1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / pyridine / dimethylformamide / 1.) 0 deg C, 30 min 2.) RT, 9 h

2: 58 percent / Ph₃P, diethylazodicarboxylate, molecular sieves (3 Angstroem) / Molecular sieves / toluene / 14 h / Ambient temperature

With pyridine; 3 A molecular sieve; triphenylphosphine; diethylazodicarboxylate; molecular sieve; In N,N-dimethyl-formamide; toluene;

Reference yield:

: 107960-18-9,110453-99-1
(2S,3R,4S,5S)-2,3,4-Tris-benzyloxy-5-ethylsulfanyl-5-hydroxymethyl-cyclohexanol

: 110372-64-0
1D-(1,2,4S/2,4C)-1,2,3-Tri-O-benzyl-4-C-<(tert-butyldimethylsilyloxy)methyl>-4-C-(ethylthio)-5-cyclohexen-1,2,3-triol

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / pyridine / dimethylformamide / 1.) 0 deg C, 30 min 2.) RT, 9 h

2: 58 percent / Ph₃P, diethylazodicarboxylate, molecular sieves (3 Angstroem) / Molecular sieves / toluene / 14 h / Ambient temperature

With pyridine; 3 A molecular sieve; triphenylphosphine; diethylazodicarboxylate; molecular sieve; In N,N-dimethyl-formamide; toluene;