o-nitrophenyl tert-butyl sulfide

Base Information

• Chemical Name: o-nitrophenyl tert-butyl sulfide
• CAS No.: 151132-35-3
• Molecular Formula: C₁₀H₁₃NO₂S
• Molecular Weight: 211.285
• Mol file: 151132-35-3.mol

Synonyms:o-nitrophenyl tert-butyl sulfide

Chemical Property of o-nitrophenyl tert-butyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of o-nitrophenyl tert-butyl sulfide

There total 8 articles about o-nitrophenyl tert-butyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2-methylpropan-2-thiol (75-66-1) + ortho-nitrofluorobenzene (1493-27-2,127723-77-7) → o-nitrophenyl tert-butyl sulfide (151132-35-3)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 2h;

Reference yield: 70.0%

sodium tert-butyl thiolate (29364-29-2) + 2-Chloronitrobenzene (88-73-3) → o-aminophenyl tert-butyl sulfide (51942-41-7) + 1-amino-2-chloro-4-<(1,1-dimethylethyl)thio>benzene (75794-24-0) + o-nitrophenyl tert-butyl sulfide (151132-35-3)

Guidance literature:

In isopropyl alcohol; at 50 ℃; for 24h; Product distribution; Kinetics; Thermodynamic data; mechanism; E_a; other temperatures; with 18-crown-6;

DOI:10.1021/jo00013a037

Reference yield:

o-nitroiodobenzene (609-73-4) → o-nitrophenyl tert-butyl sulfide (151132-35-3) + nitrobenzene (98-95-3,26969-40-4)

Guidance literature:

With sodium tert-butyl thiolate; isopropyl alcohol; at 40 ℃;

DOI:10.1021/jo00073a020

upstream raw materials:

2-nitrophenyl bromide

sodium tert-butyl thiolate

o-nitroiodobenzene

2-Chloronitrobenzene

Downstream raw materials:

(R)-(+)-2-phenyl-2,3-dihydrobenzo[d]imidazo[2,1-b]thiazole

(2S,3R)-3-isopropyl-2-phenyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine

o-aminophenyl tert-butyl sulfide