N-Methyl-N-nitrosohexanamide

Base Information

• Chemical Name: N-Methyl-N-nitrosohexanamide
• CAS No.: 16395-82-7
• Molecular Formula: C₇H₁₄N₂O₂
• Molecular Weight: 158.2
• Hs Code.: 2924199090
• Mol file: 16395-82-7.mol

Synonyms:N-Methyl-N-nitrosocaproamide;N-Methyl-N-nitrosohexanamide; N-Nitroso-N-methylcaproamide

Chemical Property of N-Methyl-N-nitrosohexanamide

Chemical Property:

• Vapor Pressure: 0.279mmHg at 25°C
• Boiling Point: 203.3°C at 760 mmHg
• Flash Point: 76.8°C
• PSA: 49.74000
• Density: 1.03g/cm³
• LogP: 1.70650

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-Methyl-N-nitrosohexanamide

There total 3 articles about N-Methyl-N-nitrosohexanamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N-methylhexanoylamide (3418-05-1) → N-methyl-N-nitrosohexanoylamide (16395-82-7)

Guidance literature:

With (25,26,27,28-tetra(n-hexyl)calix[4]arene)*NO⁺*NO₃^-*SnCl₄; In chloroform; at 20 ℃; for 5h;

DOI:10.1021/ol0342195

Reference yield:

Hexanoyl chloride (142-61-0) → N-methyl-N-nitrosohexanoylamide (16395-82-7)

Guidance literature:

Multi-step reaction with 2 steps

1: aq. K₂CO₃ / ethyl acetate

2: 95 percent Spectr_. / calixarene-nitrosonium complex / CH₂Cl₂ / 20 °C

With calixarene-nitrosonium; potassium carbonate; In dichloromethane; ethyl acetate;

DOI:10.1002/chem.200400939

Reference yield:

→ N-methyl-N-nitrosohexanoylamide (16395-82-7)

Guidance literature:

Amid, HNO2;

upstream raw materials:

N-methylhexanoylamide

Hexanoyl chloride

Downstream raw materials:

N-methylhexanoylamide

Refernces

• 1、 Kang, Yanlong,Zyryanov, Grigory V.,Rudkevich, Dmitry M.. "Towards supramolecular fixation of NOx gases: Encapsulated reagents for nitrosation". . p. 1924 - 1932. Retrieved 2007/10/03.