[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆

Base Information

Chemical Name:[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆
CAS No.:494831-09-3
Molecular Formula:C₄₁H₄₂NO₂P₂Pd*F₆P
Molecular Weight:894.122
Hs Code.:

[Pd(2,3-(MeO)2C<sub>6</sub>H<sub>2</sub>CH=N(Cy)-C<sub>6</sub>,N)((Ph<sub>2</sub>P)2CCH<sub>2</sub>-P,P')]PF<sub>6</sub>

Synonyms:[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆

Suppliers and Price of [Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆

There total 1 articles about [Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: ammonium hexafluorophosphate

: 494831-06-0
[Pd(2,3-(MeO)2C6H2CH=N(Cy)-C6,N)(μ-Cl)]2

: 84494-89-3
1,1-bis-(diphenylphosphino)ethene

: 494831-09-3
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆

Guidance literature:: In water; acetone; under Ar, 2 equiv. of P-compd. was added to Me2CO soln. of Pd-compd., stirring at room temp. for 30 min, NH4PF6 was added, stirring for 30 min, H2O was added, stirring for 12 h; ppt. was filtered off, washed twice with water, dried in vac. over CaCl2, recrystn. from CHCl3 by gaseous Et2O diffusion;
DOI:10.1039/b203864a

Reference yield: 95.0%

: 494831-09-3
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆

: 34097-60-4
methyl benzenesulfonylacetate

: C₅₀H₅₂NO₆P₂PdS⁽¹⁺⁾*F₆P^(1-)

Guidance literature:: With sodium carbonate; In chloroform; at 45 ℃; for 16h; Inert atmosphere;
DOI:10.1016/j.jorganchem.2012.07.021

Reference yield: 95.0%

: 494831-09-3
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]PF₆

: 123-54-6,81235-32-7
acetylacetone

: 494831-14-0
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CHCH₂CH(COMe)2-P,P')]PF₆

Guidance literature:: sodium carbonate; In chloroform; under Ar, 2 equiv. of acetylacetone, heating in dry CHCl3 at 45 °C for 2 h in the presence of anhyd. Na2CO3; soln. was cooled to room temp., filtered through Celite, evapd. in vac.,residue was triturated with Et2O, filtered off, washed with cold Et2O, dried in vac.;
DOI:10.1039/b203864a