(2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

Base Information

Chemical Name:(2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran
CAS No.:925222-26-0
Molecular Formula:C₁₈H₂₈O₅Se
Molecular Weight:403.377
Hs Code.:

Synonyms:(2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

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Chemical Property of (2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

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Technology Process of (2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

There total 3 articles about (2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 925222-25-9
(2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

: 925222-26-0
(2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

Guidance literature:: With sodium hydroxide; In methanol; at 20 ℃; for 24h;
DOI:10.1021/jo0615145

Reference yield:

: 925222-24-8
(2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-5-hydroxy-4-methoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

: 925222-26-0
(2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / P₂O₅ / CH₂Cl₂ / 3 h

2: 98 percent / NaOH / methanol / 24 h / 20 °C

With sodium hydroxide; phosphorus pentoxide; In methanol; dichloromethane;
DOI:10.1021/jo0615145

Reference yield:

: 925222-08-8
(2S,4S,5S,6R)-5-benzoyloxy-3,3-dimethyl-6-{[(1,1-dimethylethyl)diphenylsilyl]oxy}methyl-4-methoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

: 925222-26-0
(2S,4S,5S,6R)-3,3-dimethyl-6-hydroxymethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / tetrabutylammonium fluoride / tetrahydrofuran / 8 h / 20 °C

2: 98 percent / P₂O₅ / CH₂Cl₂ / 3 h

3: 98 percent / NaOH / methanol / 24 h / 20 °C

With sodium hydroxide; tetrabutyl ammonium fluoride; phosphorus pentoxide; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/jo0615145