(2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

Base Information

Chemical Name:(2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran
CAS No.:925222-25-9
Molecular Formula:C₂₅H₃₂O₆Se
Molecular Weight:507.485
Hs Code.:

Synonyms:(2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

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Technology Process of (2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

There total 2 articles about (2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 925222-24-8
(2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-5-hydroxy-4-methoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

: 109-87-5
Dimethoxymethane

: 925222-25-9
(2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

Guidance literature:: With phosphorus pentoxide; In dichloromethane; for 3h;
DOI:10.1021/jo0615145

Reference yield:

: 925222-08-8
(2S,4S,5S,6R)-5-benzoyloxy-3,3-dimethyl-6-{[(1,1-dimethylethyl)diphenylsilyl]oxy}methyl-4-methoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

: 925222-25-9
(2S,4S,5S,6R)-6-(benzoyloxymethyl)-3,3-dimethyl-4-methoxy-5-methoxymethoxy-2-(phenylselenyl)methyl-2H-tetrahydropyran

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / tetrabutylammonium fluoride / tetrahydrofuran / 8 h / 20 °C

2: 98 percent / P₂O₅ / CH₂Cl₂ / 3 h

With tetrabutyl ammonium fluoride; phosphorus pentoxide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo0615145