(η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium

Base Information

Chemical Name:(η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium
CAS No.:98714-10-4
Molecular Formula:C₂₇H₂₇N₂Rh
Molecular Weight:482.43
Hs Code.:

Synonyms:(η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium

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Chemical Property of (η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium

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Technology Process of (η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium

There total 1 articles about (η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 2556-46-9,141417-98-3
N,N'-diphenylbenzamidine

: 98714-10-4
(η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium

Guidance literature:: With KOH; In methanol; to the soln. of KOH and PhNCPhNHPh was added Rh complex, suspn. was heated under reflux with stirring for 1 h; the solvent was removed, extn. with CH2Cl2, pptn. with methanol, elem. anal.;

Reference yield: 87.0%

: 98714-10-4
(η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium

: 2Rh⁽¹⁺⁾*4CO*2C₆H₅C(NC₆H₅)2^(1-)=[Rh₂(C(C₆H₅)(N(C₆H₅))2)2(CO)4]

Guidance literature:: With CO; In dichloromethane; CO was bubbled through the soln. of Rh complex for 0.5 h; the solvent was removed in vacuo, pptn. with methanol-water, recrystd. from hexane, elem. anal.;

Reference yield: 70.0%

: 98714-10-4
(η-cycloocta-1,5-diene)(N,N'-diphenylbenzamidinato-N,N')rhodium

: Rh⁽¹⁺⁾*(C₆H₅)NC(C₆H₅)NH(C₆H₅)*C₈H₁₂*P(C₆H₅)3*ClO₄^(1-)=(Rh((C₆H₅)NC(C₆H₅)NH(C₆H₅))(C₈H₁₂)(P(C₆H₅)3))(ClO₄)

Guidance literature:: With P(C₆H₅)3; HClO₄; In dichloromethane; phosphine and HClO4 were added to the soln. of Rh complex, the mixt. was stirred for 0.5 h; pptn. with ether, elem. anal.;