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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Base Information Edit
  • Chemical Name:Chloro(1,5-cyclooctadiene)rhodium(I) dimer
  • CAS No.:12092-47-6
  • Molecular Formula:C16H24Cl2Rh2
  • Molecular Weight:493.084
  • Hs Code.:28439000
  • European Community (EC) Number:235-157-6
  • UNII:7BR4HR5Q6M
  • Mol file:12092-47-6.mol
Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Synonyms:(1,5-Cyclooctadiene)rhodium chloride dimer;Bis((1,5-cyclooctadiene)(chloro)rhodium);Bis((m-chloro)(h4-1,5-cyclooctadiene)rhodium);Dichlorobis(1,5-cyclooctadiene)rhodium(I);Rhodium 1,5-cyclooctadiene chloridedimer;Rhodium,di-m-chlorobis(1,5-cyclooctadiene)di-(8CI);Bis(chloro(1,5-cyclooctadiene)rhodium);Bis(cyclooctadiene)dichlorodirhodium;Bis(cyclooctadienerhodium chloride);Bis(m-chloro)bis(1,5-cyclooctadiene)dirhodium;Bis(m2-chloro)bis(1,5-cyclooctadiene)dirhodium;Chloro(cyclooctadiene)rhodium dimer;Di-m-Chlorobis(1,5-cyclooctadiene)dirhodium;Di-m-chlorobis(h4-1,5-cyclooctadiene)dirhodium(I);

Suppliers and Price of Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
  • 500mg
  • $ 180.00
  • TCI Chemical
  • Chloro(1,5-cyclooctadiene)rhodium(I) Dimer >98.0%(T)
  • 1g
  • $ 315.00
  • TCI Chemical
  • Chloro(1,5-cyclooctadiene)rhodium(I) Dimer >98.0%(T)
  • 100mg
  • $ 53.00
  • SynQuest Laboratories
  • Chloro(cycloocta-1,5-diene)rhodium(I) dimer 98%
  • 250 mg
  • $ 120.00
  • Strem Chemicals
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98%
  • 250mg
  • $ 106.00
  • Strem Chemicals
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98%
  • 1g
  • $ 304.00
  • Strem Chemicals
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98%
  • 5g
  • $ 1148.00
  • Sigma-Aldrich
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer 98%
  • 50g
  • $ 4960.00
  • Sigma-Aldrich
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer 98%
  • 5g
  • $ 784.00
  • Sigma-Aldrich
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer 98%
  • 2g
  • $ 766.00
Total 163 raw suppliers
Chemical Property of Chloro(1,5-cyclooctadiene)rhodium(I) dimer Edit
Chemical Property:
  • Appearance/Colour:orange crystals 
  • Vapor Pressure:0Pa at 25℃ 
  • Melting Point:243 °C (dec.)(lit.) 
  • Boiling Point:153.5 °C at 760 mmHg 
  • Flash Point:31.7 °C 
  • PSA:0.00000 
  • Density:1.94[at 20℃] 
  • LogP:-0.64640 
  • Storage Temp.:2-8°C 
  • Sensitive.:Air Sensitive & Hygroscopic 
  • Solubility.:Soluble in chloroform, dichloromethane, and methanol. Sparingly  
  • Water Solubility.:1.56g/L at 20℃ 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:2
  • Rotatable Bond Count:0
  • Exact Mass:491.93649
  • Heavy Atom Count:20
  • Complexity:72.6
Purity/Quality:

99% *data from raw suppliers

Chloro(1,5-cyclooctadiene)rhodium(I) Dimer *data from reagent suppliers

Safty Information:
  • Pictogram(s): IrritantXi 
  • Hazard Codes:Xi 
  • Statements: 36/37/38 
  • Safety Statements: 26-37/39 
MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Rh].[Rh]
  • Isomeric SMILES:C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.[Cl-].[Cl-].[Rh].[Rh]
  • Uses It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis. Chloro(1,5-cyclooctadiene)rhodium(I) dimer ([Rh(COD)Cl]2) can be:Employed for the synthesis of rhodium complex of heterocyclic carbenes (NHCs).Modified and coated on the surface of ferrite magnetic nanoparticles for catalyzing hydroformylation reaction of olefins. Used for the synthesis of triple-layer structure to be used as a ring-opening polymerization catalyst.As an effective catalyst for dehydrogenation of amine-borane adducts (hydrogen storage materials) such as ammonia-borane.
Technology Process of Chloro(1,5-cyclooctadiene)rhodium(I) dimer

There total 39 articles about Chloro(1,5-cyclooctadiene)rhodium(I) dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
In dichloromethane; (N2), after addn. stirred for 2 h, reduced volume, added petroleum ether-diethyl ether (1:1); filtered, washed with diethyl ether, dried in vac., ((C8H12)RhCl)2 recovered from mother liquor; elem. anal.;
Guidance literature:
In ethanol; water; react. in ethanol/water in a sealed Teflon container (microwave oven, 2450 MHz, 500 W, 50 sec);
DOI:10.1016/0022-328X(89)85418-X
Guidance literature:
With cyclooctadiene; In ethanol; water; in a modified reflux microwave apparatus RhCl3 reacts with cyclooctadiene in EtOH-H2O (5:1) (react. time: 25 min);
DOI:10.1016/0022-328X(90)87135-Z
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