Chloromethanesulfonyl fluoride

Base Information

• Chemical Name: Chloromethanesulfonyl fluoride
• CAS No.: 373-93-3
• Molecular Formula: CH2ClFO2S
• Molecular Weight: 0
• Hs Code.: 2904909090
• Mol file: 373-93-3.mol

Synonyms:chloro-methanesulfonyl fluoride;Methanesulphonyl fluoride,chloro;Chlor-methansulfonylfluorid;Chlormethansulfonsaeure-fluorid;Methanesulfonyl fluoride,chloro;Chloromethanesulphonyl fluoride;

Chemical Property of Chloromethanesulfonyl fluoride

Chemical Property:

• Vapor Pressure: 0.469mmHg at 25°C
• Boiling Point: 200°C at 760 mmHg
• Flash Point: 74.8°C
• PSA: 42.52000
• Density: 1.598g/cm³
• LogP: 1.56280

Purity/Quality:

99% ^*data from raw suppliers

CHLOROMETHANESULFONYL FLUORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Chloromethanesulfonyl fluoride

There total 1 articles about Chloromethanesulfonyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

monochloromethanesulfonyl chloride (3518-65-8) → chloromethanesulfonyl fluoride (373-93-3)

Guidance literature:

With potassium fluoride; water;

Reference yield: 91.0%

chloromethanesulfonyl fluoride (373-93-3) + 4-methoxy-trans-cinnamaldehyde (24680-50-0,71277-11-7,1963-36-6) → (1Z,3E)-1-chloro-4-(4-methoxyphenyl)buta-1,3-diene-1-sulfonyl fluoride

Guidance literature:

4-methoxy-trans-cinnamaldehyde; With pyrrolidine; In tetrahydrofuran; for 0.0833333h;

chloromethanesulfonyl fluoride; In tetrahydrofuran; at 20 ℃; for 0.333333h; stereoselective reaction;

DOI:10.1021/acs.joc.0c01877

Reference yield: 89.0%

chloromethanesulfonyl fluoride (373-93-3) + (E)-3-(2-methoxyphenyl)propenal (60125-24-8) → (1Z,3E)-1-chloro-4-(2-methoxyphenyl)buta-1,3-diene-1-sulfonyl fluoride

Guidance literature:

(E)-3-(2-methoxyphenyl)propenal; With pyrrolidine; In tetrahydrofuran; for 0.0833333h;

chloromethanesulfonyl fluoride; In tetrahydrofuran; at 20 ℃; for 0.333333h; stereoselective reaction;

DOI:10.1021/acs.joc.0c01877

upstream raw materials:

monochloromethanesulfonyl chloride

Refernces

• 1、 Zhang, Zai-Wei,Wang, Shi-Meng,Fang, Wan-Yin,Lekkala, Ravindar,Qin, Hua-Li. "Protocol for Stereoselective Construction of Highly Functionalized Dienyl Sulfonyl Fluoride Warheads". . p. 13721 - 13734. Retrieved 2020/12/15.