(Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane

Base Information

Chemical Name:(Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane
CAS No.:383194-63-6
Molecular Formula:C₂₂H₃₄OSi
Molecular Weight:342.597
Hs Code.:

Synonyms:(Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane

Suppliers and Price of (Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane

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Technology Process of (Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane

There total 5 articles about (Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 563-47-3
3-Chloro-2-methylpropene

: 383194-56-7
(Z)-2-[3-phenyl-1-(trimethylsilyl)propan-1-ylidene]-1-cyclohexanol

: 383194-63-6
(Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane

Guidance literature:: With copper (I) tert-butoxide; In tetrahydrofuran; for 23h;
DOI:10.1021/ol016837w

Reference yield:

: 482357-88-0
(Z)-2-[3-phenyl-1-(trimethylsilyl)propan-1-ylidene]cyclohexanone

: 383194-63-6
(Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / LiAlH₄ / tetrahydrofuran / 5 h / -78 °C

2: 92 percent / CuI; t-BuOLi / tetrahydrofuran; dimethylformamide / 2 h / 20 °C

With copper(l) iodide; lithium aluminium tetrahydride; lithium tert-butoxide; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo025973r

Reference yield:

: 6651-36-1
1-(Trimethylsilyloxy)cyclohexene

: 383194-63-6
(Z)-1-(3-methyl-1-phenethylbut-3-en-1-ylidene)-2-(trimethylsiloxy)cyclohexane

Guidance literature:: Multi-step reaction with 4 steps

1: 91 percent / SnCl₄ / CH₂Cl₂ / 12 h / -78 °C

2: 77 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 120 h / 0 °C

3: 86 percent / LiAlH₄ / tetrahydrofuran / 5 h / -78 °C

4: 92 percent / CuI; t-BuOLi / tetrahydrofuran; dimethylformamide / 2 h / 20 °C

With copper(l) iodide; lithium aluminium tetrahydride; tin(IV) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium tert-butoxide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo025973r