(1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Base Information

Chemical Name:(1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate
CAS No.:121408-81-9
Molecular Formula:C₂₁H₃₃NO₅
Molecular Weight:379.497
Hs Code.:

Synonyms:(1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Suppliers and Price of (1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

There total 4 articles about (1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 118759-56-1
(1Z,3S,4S,5R)-5-Benzyloxy-4-hydroxy-3-methyl-1-hexenyl N,N-diisopropylcarbamate

: 121408-81-9
(1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Guidance literature:: With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In dichloromethane; 1,2-dichloro-ethane; at 25 ℃; for 15h;
DOI:10.1055/s-1989-27159

Reference yield:

: 53346-05-7,41954-96-5,81445-44-5,81445-45-6
(R)-2-benzyloxypropanal

: 121408-81-9
(1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether / 16 h / -78 °C

2: tBuOOH / 2 mol-percent VO(acac)2 / CH₂Cl₂ / 16 h / 0 degC to 20 degC

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In diethyl ether; dichloromethane;

Reference yield:

: 100-39-0
benzyl bromide

: 121408-81-9
(1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate

Guidance literature:: Multi-step reaction with 4 steps

1: silver(I) oxide / diethyl ether / 1.5 h / Heating

2: 72 percent / DIBAH / diethyl ether; hexane / 2 h / -70 °C

4: 76 percent / VO(acac)2, t-BuOOH / CH₂Cl₂; 1,2-dichloro-ethane / 15 h / 25 °C

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; diisobutylaluminium hydride; silver(l) oxide; In diethyl ether; hexane; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1055/s-1989-27159