4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid)

Base Information

• Chemical Name: 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid)
• CAS No.: 177536-70-8
• Molecular Formula: C₂₀H₂₃N₃O₅S
• Molecular Weight: 417.486
• Mol file: 177536-70-8.mol

Synonyms:4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid)

Chemical Property of 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid)

There total 4 articles about 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

allyl bromide (106-95-6) + 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-methylsulfonsaeureamid) (177536-69-5) → 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid) (177536-70-8)

Guidance literature:

With potassium carbonate; In acetone; for 16h; Heating;

DOI:10.1002/prac.19963380126

Reference yield:

N-methyl-4-nitro-benzenesulfonamide (6319-45-5) → 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid) (177536-70-8)

Guidance literature:

Multi-step reaction with 4 steps

1: 64 percent / NaOH, NH₄Cl, Zn / H₂O / 0.67 h / 70 °C

2: 52 percent / acetic acid / 48 h / Ambient temperature

3: 94 percent / toluene / 1.5 h / Heating

4: 94 percent / K₂CO₃ / acetone / 16 h / Heating

With sodium hydroxide; potassium carbonate; ammonium chloride; zinc; In water; acetic acid; acetone; toluene;

DOI:10.1002/prac.19963380126

Reference yield:

N-Methyl-4-nitrosobenzolsulfonsaeureamid (177536-49-1) → 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid) (177536-70-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 52 percent / acetic acid / 48 h / Ambient temperature

2: 94 percent / toluene / 1.5 h / Heating

3: 94 percent / K₂CO₃ / acetone / 16 h / Heating

With potassium carbonate; In acetic acid; acetone; toluene;

DOI:10.1002/prac.19963380126

upstream raw materials:

allyl bromide

4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-methylsulfonsaeureamid)

N-methyl-4-nitro-benzenesulfonamide

N-Methyl-4-nitrosobenzolsulfonsaeureamid