N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate

Base Information

Chemical Name:N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate
CAS No.:1280126-09-1
Molecular Formula:C₉H₁₃FNOS*F₆P
Molecular Weight:347.237
Hs Code.:

Synonyms:N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate

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Chemical Property of N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate

Chemical Property:

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Technology Process of N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate

There total 7 articles about N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1280126-07-9
N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate

: 1280126-09-1
N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate

Guidance literature:: With potassium hexafluorophosphate; In dichloromethane; water; Inert atmosphere;
DOI:10.1002/anie.201006218

Reference yield:

: 100-68-5
methyl-phenyl-thioether

: 1280126-09-1
N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate

Guidance literature:: Multi-step reaction with 7 steps

1.1: N-chloro-succinimide / tetrachloromethane / 11 h / 20 °C

2.1: potassium fluoride; 18-crown-6 ether / acetonitrile / 168 h / Reflux

3.1: N-Bromosuccinimide; water / methanol / 0.5 h / 20 °C

4.1: sodium azide; sulfuric acid / chloroform / 0 - 20 °C / Inert atmosphere

5.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere

5.2: 1 h / 20 °C / Inert atmosphere

6.1: 11 h / 20 °C / Neat (no solvent); Inert atmosphere

7.1: potassium hexafluorophosphate / dichloromethane; water / Inert atmosphere

With potassium hexafluorophosphate; potassium fluoride; N-chloro-succinimide; N-Bromosuccinimide; sodium azide; 18-crown-6 ether; sulfuric acid; water; In methanol; tetrachloromethane; dichloromethane; chloroform; water; acetonitrile;
DOI:10.1002/anie.201006218

Reference yield:

: 1280126-02-4
(fluoromethyl)(imino)(phenyl)-λ⁶-sulfanone

: 1280126-09-1
N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate

Guidance literature:: Multi-step reaction with 3 steps

1.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere

1.2: 1 h / 20 °C / Inert atmosphere

2.1: 11 h / 20 °C / Neat (no solvent); Inert atmosphere

3.1: potassium hexafluorophosphate / dichloromethane; water / Inert atmosphere

With potassium hexafluorophosphate; In dichloromethane; water;
DOI:10.1002/anie.201006218