N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate

Base Information

Chemical Name:N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate
CAS No.:1280126-07-9
Molecular Formula:CF₃O₃S*C₉H₁₃FNOS
Molecular Weight:351.343
Hs Code.:

Synonyms:N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate

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Chemical Property of N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate

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Technology Process of N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate

There total 6 articles about N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 118268-17-0
α-fluoromethyl-N-methyl-phenylsulphoximine

: 333-27-7
methyl trifluoromethanesulfonate

: 1280126-07-9
N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate

Guidance literature:: at 20 ℃; for 11h; Neat (no solvent); Inert atmosphere;
DOI:10.1002/anie.201006218

Reference yield:

: 60839-94-3
2-fluoro-methylthiobenzene

: 1280126-07-9
N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 4 steps

1.1: N-Bromosuccinimide; water / methanol / 0.5 h / 20 °C

2.1: sodium azide; sulfuric acid / chloroform / 0 - 20 °C / Inert atmosphere

3.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere

3.2: 1 h / 20 °C / Inert atmosphere

4.1: 11 h / 20 °C / Neat (no solvent); Inert atmosphere

With N-Bromosuccinimide; sodium azide; sulfuric acid; water; In methanol; dichloromethane; chloroform;
DOI:10.1002/anie.201006218

Reference yield:

: 7205-91-6
phenylthiomethyl chloride

: 1280126-07-9
N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 5 steps

1.1: potassium fluoride; 18-crown-6 ether / acetonitrile / 168 h / Reflux

2.1: N-Bromosuccinimide; water / methanol / 0.5 h / 20 °C

3.1: sodium azide; sulfuric acid / chloroform / 0 - 20 °C / Inert atmosphere

4.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere

4.2: 1 h / 20 °C / Inert atmosphere

5.1: 11 h / 20 °C / Neat (no solvent); Inert atmosphere

With potassium fluoride; N-Bromosuccinimide; sodium azide; 18-crown-6 ether; sulfuric acid; water; In methanol; dichloromethane; chloroform; acetonitrile;
DOI:10.1002/anie.201006218