[1,3-bis(diphenylphosphino)propane]Pd-MeCl

Base Information

Chemical Name:[1,3-bis(diphenylphosphino)propane]Pd-MeCl
CAS No.:139168-07-3
Molecular Formula:C₂₉H₃₁ClP₂Pd
Molecular Weight:583.386
Hs Code.:

Synonyms:[1,3-bis(diphenylphosphino)propane]Pd-MeCl

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Chemical Property of [1,3-bis(diphenylphosphino)propane]Pd-MeCl

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Technology Process of [1,3-bis(diphenylphosphino)propane]Pd-MeCl

There total 1 articles about [1,3-bis(diphenylphosphino)propane]Pd-MeCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: chloromethyl(1,5-cyclooctadiene)palladium(II)

: 7688-25-7
1,4-di(diphenylphosphino)-butane

: 139168-07-3
[1,3-bis(diphenylphosphino)propane]Pd-MeCl

Guidance literature:: In benzene; addn. of equimolar amt. of the ligand to soln. of (C8H12)Pd(CH3)Cl in benzene (under N2), stirred (1 h); ppt. filtered off, washed (benzene, pentane), recrystd. (CH2Cl2/ Et2O); elem. anal.;
DOI:10.1021/om00040a034

Reference yield: 88.0%

: 139168-07-3
[1,3-bis(diphenylphosphino)propane]Pd-MeCl

: 2923-28-6
silver trifluoromethanesulfonate

: 139168-29-9
(C₆H₅)2P(CH₂)4P(C₆H₅)2*CH₃CN*Pd⁽²⁺⁾*CH₃^(1-)*SO₃CF₃^(1-)={((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(CH₃)(CH₃CN)}(SO₃CF₃)

Guidance literature:: With acetonitrile; In dichloromethane; acetonitrile; byproducts: AgCl; dropwise addn. of AgSO3CF3 in CH3CN to a rapidly stirred soln. of the Pd complex in CH2Cl2/CH3CN (under N2); filtered, filtrate collected in Et2O (-20°C, rapid stirring), ppt. filtered off, washed (benzene, pentane), recrystd. (CH2Cl2/ Et2O); product mixt. of monomeric and oligomeric complexes (NMR) obtained; elem. anal.;
DOI:10.1021/om00040a034

Reference yield:

: 139168-07-3
[1,3-bis(diphenylphosphino)propane]Pd-MeCl

: 139168-10-8
((C₆H₅)2P(CH₂)4P(C₆H₅)2)Pd(C(O)CH₃)Cl

Guidance literature:: With carbon monoxide; In dichloromethane-d2; High Pressure; Pd complex dissolved in CD2Cl2 (under N2, high-pressure NMR tube), 25 bar of CO applied (235 K); not isolated; (1)H- and (31)P-NMR; Kinetics;
DOI:10.1021/om00040a034