4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone

Base Information

Chemical Name:4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone
CAS No.:153399-43-0
Molecular Formula:C₂₇H₂₅BrO₆
Molecular Weight:525.396
Hs Code.:

Synonyms:4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone

Suppliers and Price of 4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone

There total 6 articles about 4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 153399-42-9
C₂₈H₂₈O₇

: 153399-43-0
4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone

Guidance literature:: With boron tribromide; In dichloromethane; at -70 ℃; for 0.5h;
DOI:10.1246/cl.1993.1895

Reference yield:

: 18065-05-9
1-[2,4-bis(benzyloxy)-6-hydroxyphenyl]ethanone

: 153399-43-0
4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone

Guidance literature:: Multi-step reaction with 6 steps

1: 83 percent / I₂, silver trifluoroacetate / CHCl₃ / Ambient temperature

2: K₂CO₃ / acetone

3: 95 percent / PdCl₂, CuI, PPh₃, Et₃N / dimethylformamide / 15 h / 80 - 85 °C

4: H₂ / Pd/C / methanol / 20 °C

5: K₂CO₃ / acetone

6: 79 percent / BBr₃ / CH₂Cl₂ / 0.5 h / -70 °C

With copper(l) iodide; hydrogen; iodine; silver trifluoroacetate; boron tribromide; potassium carbonate; triethylamine; triphenylphosphine; palladium dichloride; palladium on activated charcoal; In methanol; dichloromethane; chloroform; N,N-dimethyl-formamide; acetone;
DOI:10.1246/cl.1993.1895

Reference yield:

: 95165-66-5
3-Iod-2-hydroxy-4,6-dibenzyloxy-acetophenon

: 153399-43-0
4',6'-bis(benzoyloxy)-3'-(3-bromo-3-methylbutyl)-2'-hydroxyacetophenone

Guidance literature:: Multi-step reaction with 5 steps

1: K₂CO₃ / acetone

2: 95 percent / PdCl₂, CuI, PPh₃, Et₃N / dimethylformamide / 15 h / 80 - 85 °C

3: H₂ / Pd/C / methanol / 20 °C

4: K₂CO₃ / acetone

5: 79 percent / BBr₃ / CH₂Cl₂ / 0.5 h / -70 °C

With copper(l) iodide; hydrogen; boron tribromide; potassium carbonate; triethylamine; triphenylphosphine; palladium dichloride; palladium on activated charcoal; In methanol; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1246/cl.1993.1895