2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone

Base Information

Chemical Name:2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone
CAS No.:320371-93-5
Molecular Formula:C₃₀H₄₂O₁₂
Molecular Weight:594.656
Hs Code.:

Synonyms:2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone

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Chemical Property of 2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone

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Technology Process of 2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone

There total 3 articles about 2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 189825-52-3
(2R,3R,4S,5R)-3,4,5-tris(methoxymethoxy)-2-((methoxymethoxy)methyl)-6-methylenetetrahydro-2H-pyran

: 320371-89-9
1-(2-bromo-phenyl)-2-(4-methoxy-phenoxy)-ethanone

: 320371-93-5
2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone

: 1-[2-((3S,4R,5R,6R)-6-Hydroxy-3,4,5,7-tetrakis-methoxymethoxy-heptyl)-phenyl]-2-(4-methoxy-phenoxy)-ethanone

Guidance literature:: (2R,3R,4S,5R)-3,4,5-tris(methoxymethoxy)-2-((methoxymethoxy)methyl)-6-methylenetetrahydro-2H-pyran; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; Heating;

1-(2-bromo-phenyl)-2-(4-methoxy-phenoxy)-ethanone; With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In water; N,N-dimethyl-formamide; at 20 ℃; for 18h;
DOI:10.1016/S0040-4039(00)01709-3

Reference yield:

: 2142-69-0
2-bromophenyl methyl ketone

: 320371-93-5
2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone

Guidance literature:: Multi-step reaction with 3 steps

1.1: PhMe₃NBr₃ / tetrahydrofuran

2.1: K₂CO₃ / dimethylformamide / 80 °C

3.1: 9-BBN / tetrahydrofuran / Heating

3.2: 51 percent / K₃PO₄ / Pd(dppf)*CH₂Cl₂ / H₂O; dimethylformamide / 18 h / 20 °C

With 9-borabicyclo[3.3.1]nonane dimer; phenyltrimethylammonium tribromide; potassium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide; 3.2: Suzuki coupling;
DOI:10.1016/S0040-4039(00)01709-3

Reference yield:

: 49851-55-0
2,2'-dibromoacetophenone

: 320371-93-5
2-(4-Methoxy-phenoxy)-1-[2-((2S,3S,4R,5R,6R)-3,4,5-tris-methoxymethoxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-phenyl]-ethanone

Guidance literature:: Multi-step reaction with 2 steps

1.1: K₂CO₃ / dimethylformamide / 80 °C

2.1: 9-BBN / tetrahydrofuran / Heating

2.2: 51 percent / K₃PO₄ / Pd(dppf)*CH₂Cl₂ / H₂O; dimethylformamide / 18 h / 20 °C

With 9-borabicyclo[3.3.1]nonane dimer; potassium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide; 2.2: Suzuki coupling;
DOI:10.1016/S0040-4039(00)01709-3