Technology Process of C19H24O4
There total 2 articles about C19H24O4 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sulfuric acid; mercury(II) sulfate;
In
tetrahydrofuran; water;
at 0 - 20 ℃;
DOI:10.1021/ol902217q
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.33 h / -78 °C
1.2: -78 - 20 °C
2.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate / dichloromethane / 44 h / -40 - -15 °C / Molecular sieve
2.2: 3 h / -15 - 20 °C
3.1: silica-supported sodium periodate / dichloromethane / 1.33 h / 0 - 20 °C
4.1: potassium carbonate / methanol / 1.5 h / 0 °C
5.1: sulfuric acid; water; mercury(II) sulfate / tetrahydrofuran / 4 h / 0 - 20 °C
With
titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate; silica-supported sodium periodate; sulfuric acid; water; diisobutylaluminium hydride; potassium carbonate; mercury(II) sulfate;
In
tetrahydrofuran; methanol; hexane; dichloromethane;
2.1: Sharpless epoxidation;
DOI:10.1016/j.tet.2010.11.017
- Guidance literature:
-
C19H24O4;
With
potassium hexamethylsilazane;
In
tetrahydrofuran; toluene;
at -78 - -40 ℃;
N,N-phenylbistrifluoromethane-sulfonimide;
In
tetrahydrofuran; toluene;
at -78 - -20 ℃;
DOI:10.1021/ol902217q