triphenylstannyltris(trimethylphosphane)cobalt

Base Information

• Chemical Name: triphenylstannyltris(trimethylphosphane)cobalt
• CAS No.: 86064-11-1
• Molecular Formula: C₂₇H₄₂CoP₃Sn
• Molecular Weight: 637.255
• Mol file: 86064-11-1.mol

Synonyms:triphenylstannyltris(trimethylphosphane)cobalt

Chemical Property of triphenylstannyltris(trimethylphosphane)cobalt

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of triphenylstannyltris(trimethylphosphane)cobalt

There total 4 articles about triphenylstannyltris(trimethylphosphane)cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

chlorotris(trimethylphosphane)cobalt(I) (55516-89-7) + triphenyltin chloride (639-58-7) → triphenylstannyltris(trimethylphosphane)cobalt (86064-11-1)

Guidance literature:

With Li; In tetrahydrofuran; byproducts: LiCl; under dry argon, addn. of Co-compound to a soln. of Sn-compound and Li at -78°C with stirring, slow warming to 20°C, stirring for1 h; removing solvent, addn. of ether, filtn., crystn., elem. anal.;

Reference yield: 68.0%

K(1+)*N2*Co(1-)*3(P(CH3)3)=KN2Co(P(CH3)3)3 + triphenyltin chloride (639-58-7) → triphenylstannyltris(trimethylphosphane)cobalt (86064-11-1)

Guidance literature:

In diethyl ether; byproducts: KCl, N2; under dry argon, cooling a soln. of Co-complex with liquid nitrogen, addn. of Sn-compound, stirring; filtn., crystn. at -20°C, elem. anal.;

Reference yield:

propene tris(trimethylphosphine)cobalt (73555-59-6) + triphenyltin chloride (639-58-7) → triphenylstannyltris(trimethylphosphane)cobalt (86064-11-1)

Guidance literature:

With K; In diethyl ether; byproducts: KCl, C3H6; under dry argon, stirring soln. of Co-compound with K at 20°C. for 6 h, cooling to -78°C, addn. of Sn-compound; filtn., crystn. at -20°C, elem. anal.;

upstream raw materials:

triphenyltin chloride

chlorotris(trimethylphosphane)cobalt(I)

propene tris(trimethylphosphine)cobalt

Co(cyclo-C₅H₈)PMe₃)3

Downstream raw materials:

triphenylstannyltris(trimethylphosphane)(carbonyl)cobalt

triphenylstannyltetrakis(trimethylphosphane)cobalt

triphenylstannyltris(trimethylphosphane)(C₂H₄)cobalt