(1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid

Base Information

Chemical Name:(1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid
CAS No.:1402883-85-5
Molecular Formula:C₁₅H₁₅BrO₅
Molecular Weight:355.185
Hs Code.:

Synonyms:(1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid

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Technology Process of (1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid

There total 5 articles about (1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1071-46-1
hydrogen ethyl malonate

: 1402883-85-5
(1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid

Guidance literature:: With Carbonyldiimidazole; In acetonitrile; at 20 ℃; for 0.75h;

With triethylamine; magnesium chloride; In acetonitrile; at 20 - 80 ℃; for 2.66667h;

Reference yield:

: 1402883-82-2
(1R,2S)-1-(3-bromophenyl)cyclopropane-1,2-dicarboxylic acid

: 6148-64-7
ethyl potassium malonate

: 1402883-85-5
(1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid

Guidance literature:: (1R,2S)-1-(3-bromophenyl)cyclopropane-1,2-dicarboxylic acid; With 1,1'-carbonyldiimidazole; In acetonitrile; at 20 ℃;

ethyl potassium malonate; With triethylamine; magnesium chloride; In acetonitrile; at 20 - 80 ℃;
DOI:10.1021/jm3011405

Reference yield:

: 1402883-77-5
(1R,5S)-1-(3-bromophenyl)-3-oxabicyclo[3.1.0]hexan-2-one

: 1402883-85-5
(1R,2S)-1-(3-bromophenyl)-2-(3-ethoxy-3-oxopropanoyl)cyclopropanecarboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium hydroxide / ethanol; water / 20 °C

2.1: ruthenium trichloride; sodium periodate / water; acetonitrile / 20 °C

3.1: 1,1'-carbonyldiimidazole / acetonitrile / 20 °C

3.2: 20 - 80 °C

With ruthenium trichloride; sodium periodate; 1,1'-carbonyldiimidazole; potassium hydroxide; In ethanol; water; acetonitrile;
DOI:10.1021/jm3011405