(+/-)-trans-4b,5,11b,12-tetrahydro-2,3-dimethoxy-12-methyl-<1,3>benzodioxolo<5,6-c>phenanthridine-6,13-dione

Base Information

Chemical Name:(+/-)-trans-4b,5,11b,12-tetrahydro-2,3-dimethoxy-12-methyl-<1,3>benzodioxolo<5,6-c>phenanthridine-6,13-dione
CAS No.:64036-03-9
Molecular Formula:C₂₁H₁₉NO₆
Molecular Weight:381.385
Hs Code.:

Synonyms:(+/-)-trans-4b,5,11b,12-tetrahydro-2,3-dimethoxy-12-methyl-<1,3>benzodioxolo<5,6-c>phenanthridine-6,13-dione

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Chemical Property of (+/-)-trans-4b,5,11b,12-tetrahydro-2,3-dimethoxy-12-methyl-<1,3>benzodioxolo<5,6-c>phenanthridine-6,13-dione

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Technology Process of (+/-)-trans-4b,5,11b,12-tetrahydro-2,3-dimethoxy-12-methyl-<1,3>benzodioxolo<5,6-c>phenanthridine-6,13-dione

There total 1 articles about (+/-)-trans-4b,5,11b,12-tetrahydro-2,3-dimethoxy-12-methyl-<1,3>benzodioxolo<5,6-c>phenanthridine-6,13-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5653-42-9
3,4-dimethoxyhomophthalic anhydride

: 64036-03-9
(+/-)-trans-4b,5,11b,12-tetrahydro-2,3-dimethoxy-12-methyl-<1,3>benzodioxolo<5,6-c>phenanthridine-6,13-dione

Guidance literature:: Multi-step reaction with 4 steps

1: CHCl₃

2: (i) SOCl₂, benzene, (ii) /BRN= 102415/, Et₂O

3: (i) Et₃N, PhCO₂Ag, MeOH, THF, (ii) KOH, EtOH

4: (i) O₂, polyphosphoric acid, (ii) H₂O

In chloroform;
DOI:10.1021/jo00396a024

Reference yield:

: 64036-03-9
(+/-)-trans-4b,5,11b,12-tetrahydro-2,3-dimethoxy-12-methyl-<1,3>benzodioxolo<5,6-c>phenanthridine-6,13-dione

: 548-31-2
oxynitidine

: 56221-65-9
2,3-dimethoxy-12-methyl-(4br,11bt)-5,6,11b,12-tetrahydro-4bH-[1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridin-13-one

Guidance literature:: With sodium tetrahydroborate; palladium on activated charcoal; Yield given. Multistep reaction. Yields of byproduct given; 1.) 2-propanol, RT, 3 h, 2.) acetic acid, reflux;
DOI:10.1021/jo00245a052