4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside

Base Information

• Chemical Name: 4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside
• CAS No.: 162088-87-1
• Molecular Formula: C₂₁H₃₁NO₉Si
• Molecular Weight: 469.564
• Mol file: 162088-87-1.mol

Synonyms:4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside

Chemical Property of 4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside

There total 2 articles about 4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triethylsilyl chloride (994-30-9) → 4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside (162088-87-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) dibutyltin oxide / 1.) benzene, toluene, reflux, overnight, 2.) benzene, toluene, RT, 2 d

2: pyridine

With pyridine; di(n-butyl)tin oxide;

DOI:10.1016/0008-6215(94)00214-2

Reference yield:

acetic anhydride (108-24-7) + (2S,3R,4R,5R)-2-(4-Nitro-phenoxy)-5-triethylsilanyloxy-tetrahydro-pyran-3,4-diol → 4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside (162088-87-1)

Guidance literature:

With pyridine; Yield given;

DOI:10.1016/0008-6215(94)00214-2

Reference yield: 91.0%

4'-nitrophenyl 2,3-di-O-acetyl-4-O-triethylsilyl-β-D-xylopyranoside (162088-87-1) → 1-O-(4-nitrophenyl)-2,3-di-O-acetyl-β-D-xylopyranoside (162088-88-2)

Guidance literature:

With acetic acid; In diethyl ether; water; for 3h; Ambient temperature;

DOI:10.1016/0008-6215(94)00214-2

upstream raw materials:

acetic anhydride

triethylsilyl chloride

Downstream raw materials:

1-O-(4-nitrophenyl)-2,3-di-O-acetyl-β-D-xylopyranoside

p-nitrophenyl β-D-xylopyranosyl-(1->4)-β-D-xylopyranoside

4-nitrophenyl tri-O-acetyl-β-D-xylopyranosyl-(1->4)-2,3-di-O-acetyl-β-D-xyloside