PtCl(P(C₄H₉)3)2(C₂C₆H₄C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄C₂Si(CH(CH₃)2)3)

Base Information

• Chemical Name: PtCl(P(C₄H₉)3)2(C₂C₆H₄C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄C₂Si(CH(CH₃)2)3)
• CAS No.: 1173397-60-8
• Molecular Formula: C₇₇H₁₃₇ClP₄Pt₂Si
• Molecular Weight: 1640.53
• Mol file: 1173397-60-8.mol

Synonyms:PtCl(P(C₄H₉)3)2(C₂C₆H₄C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄C₂Si(CH(CH₃)2)3)

Chemical Property of PtCl(P(C₄H₉)3)2(C₂C₆H₄C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄C₂Si(CH(CH₃)2)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PtCl(P(C₄H₉)3)2(C₂C₆H₄C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄C₂Si(CH(CH₃)2)3)

There total 1 articles about PtCl(P(C₄H₉)3)2(C₂C₆H₄C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄C₂Si(CH(CH₃)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

cis-dichlorobis(tri-n-butylphosphine)platinum(II) (15390-92-8,15391-01-2,15076-72-9) + (HCCC6H4C2)Pt(P(C4H9)3)2(C2C6H4C2Si(CH(CH3)2)3) (1173397-74-4) → PtCl(P(C4H9)3)2(C2C6H4C2)Pt(P(C4H9)3)2(C2C6H4C2Si(CH(CH3)2)3) (1173397-60-8)

Guidance literature:

With diethylamine; In diethylamine; two Pt complexes in Et2NH refluxed for 12 h; according to K. Sonogashiraet al., J. Organomet. Chem., 1978, 145, 101 and N. Hagihara et al., Adv . Polym. Sci., 1980, 40, 149;

DOI:10.1021/om900195p

Reference yield: 95.0%

PtCl(P(C4H9)3)2(C2C6H4C2)Pt(P(C4H9)3)2(C2C6H4C2Si(CH(CH3)2)3) (1173397-60-8) + 1,4-diethynylbenzene (935-14-8) → ((CH3)2CH)3SiCCC6H4((C2)Pt(P(C4H9)3)2(C2C6H4))4CCSi(CH(CH3)2)3

Guidance literature:

With diethylamine; copper(l) iodide; In tetrahydrofuran; diethylamine; Pt complex reacted with diethynylbenzene in Et2NH-THF in presence of CuIat room temp. for 4 h;

DOI:10.1021/om900195p

Reference yield: 90.0%

PtCl(P(C4H9)3)2(C2C6H4C2)Pt(P(C4H9)3)2(C2C6H4C2Si(CH(CH3)2)3) (1173397-60-8) + HCCC6H4((C2)Pt(P(C4H9)3)2(C2C6H4))4CCH (1173397-67-5) → 2((CH3)2CH)3SiCCC6H4C2(1-)*8Pt(2+)*16P(C4H9)3*7C2C6H4C2(2-)=(C3H7)3SiCCC6H4((C2)Pt(P(C4H9)3)2(C2C6H4))8CCSi(C3H7)3

Guidance literature:

With diethylamine; copper(l) iodide; In tetrahydrofuran; diethylamine; two Pt complexes reacted in Et2NH-THF in presence of CuI at room temp. for 4 h;

DOI:10.1021/om900195p

upstream raw materials:

cis-dichlorobis(tri-n-butylphosphine)platinum(II)

(HCCC₆H₄C₂)Pt(P(C₄H₉)3)2(C₂C₆H₄C₂Si(CH(CH₃)2)3)