(S_C)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide

Base Information

• Chemical Name: (S_C)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide
• CAS No.: 386768-41-8
• Molecular Formula: C₃₇H₄₇O₅P
• Molecular Weight: 602.751
• Mol file: 386768-41-8.mol

Synonyms:(S_C)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide

Chemical Property of (S_C)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S_C)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide

There total 16 articles about (S_C)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

p-hydroxyphenyl undec-10-en-1-yl ether (117721-44-5) + (SC)-7-carboxy-5-ethyl-3-(2-methylbutoxy)-5H-dibenzophosphole 5-oxide (458570-20-2) → (SC)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide (386768-41-8)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃;

DOI:10.1016/S0040-4039(01)01661-6

Reference yield:

3-bromo-5-ethyl-5H-dibenzophosphole 5-oxide (458570-14-4) → (SC)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide (386768-41-8)

Guidance literature:

Multi-step reaction with 7 steps

1.1: 100 percent / HNO₃; H₂SO₄ / 0 °C

2.1: 82 percent / iron; HCl; water / ethanol / Heating

3.1: NaNO₂; H₂SO₄; water / 0 °C

3.2: 87 percent / Cu(NO₃)2*3H₂O; Cu₂O / 20 °C

4.1: K₂CO₃ / dimethylformamide / Heating

5.1: 92 percent / PPh₃; Ca(OH)2; Pd(OAc)2 / dimethylformamide / 100 °C

6.1: 80 percent / HCl; H₂O / Heating

7.1: DCC; DMAP / CH₂Cl₂ / 20 °C

7.2: 80 percent / 20 °C

With hydrogenchloride; dmap; palladium diacetate; calcium hydroxide; sulfuric acid; water; nitric acid; iron; potassium carbonate; dicyclohexyl-carbodiimide; triphenylphosphine; sodium nitrite; In ethanol; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

3-amino-7-bromo-5-ethyl-5H-dibenzophosphole 5-oxide (458570-16-6) → (SC)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide (386768-41-8)

Guidance literature:

Multi-step reaction with 5 steps

1.1: NaNO₂; H₂SO₄; water / 0 °C

1.2: 87 percent / Cu(NO₃)2*3H₂O; Cu₂O / 20 °C

2.1: K₂CO₃ / dimethylformamide / Heating

3.1: 92 percent / PPh₃; Ca(OH)2; Pd(OAc)2 / dimethylformamide / 100 °C

4.1: 80 percent / HCl; H₂O / Heating

5.1: DCC; DMAP / CH₂Cl₂ / 20 °C

5.2: 80 percent / 20 °C

With hydrogenchloride; dmap; palladium diacetate; calcium hydroxide; sulfuric acid; water; potassium carbonate; dicyclohexyl-carbodiimide; triphenylphosphine; sodium nitrite; In dichloromethane; N,N-dimethyl-formamide;

upstream raw materials:

p-hydroxyphenyl undec-10-en-1-yl ether

(S_C)-7-carboxy-5-ethyl-3-(2-methylbutoxy)-5H-dibenzophosphole 5-oxide

9-phenyl-9-phosphafluorene

5-ethyl-5H-dibenzophosphole

Downstream raw materials:

(R_P,S_C)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole

(S_C,S_P)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole