dibenzo[b,e]thiepin-11(6H)-one 5,5-dioxide

Base Information

• Chemical Name: dibenzo[b,e]thiepin-11(6H)-one 5,5-dioxide
• CAS No.: 33301-21-2
• Molecular Formula: C₁₄H₁₀O₃S
• Molecular Weight: 258.298
• Mol file: 33301-21-2.mol

Synonyms:5,5-dioxo-6,11-dihydrodibenzothiepin-11-one;Dibenzothiepin-11-on-5,5-dioxid;11-Oxo-6,11-dihydro-dibenzthiepin-5,5-dioxid;6,11-Dihydrodibenzothiepin-11-one 5,5-dioxide;11-Oxo-6,11-dihydro-dibenzothiepin-5,5-dioxid;

Chemical Property of dibenzo[b,e]thiepin-11(6H)-one 5,5-dioxide

Chemical Property:

• Vapor Pressure: 4.92E-11mmHg at 25°C
• Boiling Point: 523°C at 760 mmHg
• Flash Point: 357.5°C
• PSA: 59.59000
• Density: 1.382g/cm³
• LogP: 3.28570

Purity/Quality:

98%min ^*data from raw suppliers

DIBENZO(B,E)THIEPIN-11(6H)-ONE 5,5-DIOXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dibenzo[b,e]thiepin-11(6H)-one 5,5-dioxide

There total 3 articles about dibenzo[b,e]thiepin-11(6H)-one 5,5-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

6,11-dihydrodibenzo[b,e]thiepin-11-ol (1745-46-6) → 6,11-Dihydrodibenzothiepin-11-one 5,5-dioxide (33301-21-2)

Guidance literature:

With peracetic acid; In acetic acid;

DOI:10.1021/jm00091a017

Reference yield:

dibenzo[b,e]thiepin-11(6H)-one (1531-77-7) → 6,11-Dihydrodibenzothiepin-11-one 5,5-dioxide (33301-21-2)

Guidance literature:

With dihydrogen peroxide; acetic acid; for 2h; Reflux;

DOI:10.1007/s00044-018-02286-1

Reference yield:

→ 6,11-Dihydrodibenzothiepin-11-one 5,5-dioxide (33301-21-2)

Guidance literature:

11-Oxo-6,11-dihydro-dibenzothiepin, 30percentig. H2O2 ;

DOI:10.1021/jm01241a012

upstream raw materials:

6,11-dihydrodibenzo[b,e]thiepin-11-ol

dibenzo[b,e]thiepin-11(6H)-one

Downstream raw materials:

1-(10,10-Dioxo-10,11-dihydro-5H-10λ⁶-thia-dibenzo[a,d]cyclohepten-5-yl)-4-((E)-3-phenyl-allyl)-piperazine; compound with oxalic acid

11-chloro-5,5-dioxo-6,11-dihydrodibenzothiepin

Refernces

• 1、 Dhainaut, Alain,Regnier, Gilbert,Atassi, Ghanem,Pierre, Alain,Leonce, Stephane,et al.. "New Triazine Derivatives as Potent Modulators of Multidrug Resistance". . p. 2481 - 2496. Retrieved 2007/10/02.