(1S,3S,4aR,5S)-5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene

Base Information

Chemical Name:(1S,3S,4aR,5S)-5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene
CAS No.:87637-85-2
Molecular Formula:C₁₉H₂₄O₂S
Molecular Weight:316.464
Hs Code.:

Synonyms:(1S,3S,4aR,5S)-5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,3S,4aR,5S)-5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene

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Technology Process of (1S,3S,4aR,5S)-5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene

There total 5 articles about (1S,3S,4aR,5S)-5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 473-00-7
2-ethylene-6,6-dimethylbicyclo<3.1.1>hept-2-ene

: 5535-48-8
PVS

: 73301-19-6,87637-85-2
5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene

Guidance literature:: In benzene; at 150 ℃; for 28h;
DOI:10.1021/ja00522a075

Reference yield: 98.0%

: 473-00-7
2-ethylene-6,6-dimethylbicyclo<3.1.1>hept-2-ene

: 5535-48-8
PVS

: 87637-85-2
(1S,3S,4aR,5S)-5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene

Guidance literature:: With hydroquinone; In benzene; at 150 ℃; for 28h;
DOI:10.1021/jo00173a039

Reference yield:

: 4837-01-8
1-bromo-2-phenylthioethane

: 87637-85-2
(1S,3S,4aR,5S)-5-Benzenesulfonyl-9,9-dimethyl-1,2,3,4,4a,5,6,7-octahydro-1,3-methano-naphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: sodium ethoxide / ethanol / 8 h / Heating

2: 78 percent / 30percent H₂O₂ / acetic acid / 1.) 70 deg C, 2.) reflux, 20 min

3: 98 percent / hydroquinone / benzene / 28 h / 150 °C

With dihydrogen peroxide; sodium ethanolate; hydroquinone; In ethanol; acetic acid; benzene;
DOI:10.1021/jo00173a039