Technology Process of ((1S,2R,3R,4S,5S,6R)-5,6-bis(nonyloxy)cyclohexane-1,2,3,4-tetrayl)tetrakis(oxy)tetrakis(methylene)tetrabenzene
There total 4 articles about ((1S,2R,3R,4S,5S,6R)-5,6-bis(nonyloxy)cyclohexane-1,2,3,4-tetrayl)tetrakis(oxy)tetrakis(methylene)tetrabenzene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
3,4,5,6-tetra-O-benzyl inositol;
With
sodium hydride;
In
N,N-dimethyl-formamide; mineral oil;
at 0 ℃;
for 0.25h;
1-iodononane;
In
N,N-dimethyl-formamide; mineral oil;
at 0 ℃;
for 3h;
DOI:10.1021/ml200098j
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 16 h / 30 °C
2.1: tert.-butylhydroperoxide; osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 20 °C
3.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.25 h / 0 °C
3.2: 3 h / 0 °C
With
tert.-butylhydroperoxide; osmium(VIII) oxide; water; sodium hydride; 4-methylmorpholine N-oxide;
In
N,N-dimethyl-formamide; acetone; mineral oil; tert-butyl alcohol;
DOI:10.1021/ml200098j
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 16 h / 30 °C
2.1: tert.-butylhydroperoxide; osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 20 °C
3.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.25 h / 0 °C
3.2: 3 h / 0 °C
With
tert.-butylhydroperoxide; osmium(VIII) oxide; water; sodium hydride; 4-methylmorpholine N-oxide;
In
N,N-dimethyl-formamide; acetone; mineral oil; tert-butyl alcohol;
DOI:10.1021/ml200098j
