cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II)

Base Information

• Chemical Name: cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II)
• CAS No.: 111848-61-4
• Molecular Formula: C₃₀H₅₉ClP₂PtSi
• Molecular Weight: 740.364
• Mol file: 111848-61-4.mol

Synonyms:cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II)

Chemical Property of cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II)

There total 1 articles about cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

cis-chloro{(trimethylsilyl)methyl}(1,5-cyclooctadiene)platinum(II) (111848-60-3) + 1,2-bis-(dicyclohexylphosphino)ethane (23743-26-2) → cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II) (111848-61-4)

Guidance literature:

In dichloromethane; addn. of bis(dicyclohexylphosphino)ethane to cis-chloro{(trimethylsilyl)methyl}(1,5-cyclooctadiene)platinum(II) in CH2Cl2, colorless soln. stirred 2 h at 25°C; solvent removed by evapn., recrystn. from hot acetone, crystn. at -10°C, suction filtration;

DOI:10.1021/ja00213a016

Reference yield: 47.0%

cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II) (111848-61-4) → cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II) (105373-20-4)

Guidance literature:

With Na{HB(OMe)3}; In tetrahydrofuran; addn. of Na{HB(OMe)3} to cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II) in THF with immediate cloudiness, after 6 h quenched by aq.NH4Cl at 0°C; layers sepd., aq. layer extd. with ether, solvent removal by evapn., resulting oil dissolved in min. of ether, 1 part methanol added, crystn. at -10°C, suction filtration;

DOI:10.1021/ja00213a016

upstream raw materials:

cis-chloro{(trimethylsilyl)methyl}(1,5-cyclooctadiene)platinum(II)

1,2-bis-(dicyclohexylphosphino)ethane

Downstream raw materials:

cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)