cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Base Information

Chemical Name:cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)
CAS No.:105373-20-4
Molecular Formula:C₃₀H₆₀P₂PtSi
Molecular Weight:705.919
Hs Code.:

Synonyms:cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)

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Chemical Property of cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)

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Technology Process of cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)

There total 4 articles about cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II)

: 75-76-3
tetramethylsilane

: 105373-20-4
cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)

: 463-82-1
2,2-dimethylpropane

Guidance literature:: In cyclohexane; thermolysis of cis-hydridoneopentyl{bis(dicyclohexylphosphino)ethane}platinum(II) in tetramethylsilane/cyclohexane via supposed {bis(dicyclohexylphosphino)ethane}platinum(0) at 69.8°C for 3 h; Kinetics;
DOI:10.1021/ja00213a016

Reference yield: 85.0%

: cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II)

: 75-76-3
tetramethylsilane

: 105373-20-4
cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Guidance literature:: In neat (no solvent); byproducts: neopentane; 69°C; NMR, elem. anal.;
DOI:10.1021/ja00285a039

Reference yield: 47.0%

: 111848-61-4
cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II)

: 105373-20-4
cis-hydrido(trimethylsilylmethyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Guidance literature:: With Na{HB(OMe)3}; In tetrahydrofuran; addn. of Na{HB(OMe)3} to cis-chloro{(trimethylsilyl)methyl}{bis(dicyclohexylphosphino)ethane}platinum(II) in THF with immediate cloudiness, after 6 h quenched by aq.NH4Cl at 0°C; layers sepd., aq. layer extd. with ether, solvent removal by evapn., resulting oil dissolved in min. of ether, 1 part methanol added, crystn. at -10°C, suction filtration;
DOI:10.1021/ja00213a016