3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

Base Information

Chemical Name:3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside
CAS No.:216871-58-8
Molecular Formula:C₃₇H₄₂O₈S
Molecular Weight:646.802
Hs Code.:

Synonyms:3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

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Chemical Property of 3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

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Technology Process of 3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

There total 2 articles about 3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 216871-53-3
3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

: 216871-58-8
3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

Guidance literature:: With disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1016/S0040-4039(98)01823-1

Reference yield:

: 72174-24-4,53269-97-9
(2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-thiol

: 216871-58-8
3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / K₂CO₃; NaI / acetone / 20 h / Heating

2: 82 percent / mCPBA; Na₂HPO₄ / CH₂Cl₂ / 0 - 20 °C

With disodium hydrogenphosphate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; sodium iodide; In dichloromethane; acetone;
DOI:10.1002/1099-0690(200204)2002:7<1323::AID-EJOC1323>3.0.CO;2-8

Reference yield: 74.0%

: 216871-58-8
3'-hydroxyprop-1'-yl S,S-dioxo-2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

: 4,8-anhydro-5,6,7,9-tetra-O-benzyl-2,3-dideoxy-D-gluco-non-3-enitol

Guidance literature:: With aluminum oxide; potassium hydroxide; dibromodifluoromethane; In dichloromethane; tert-butyl alcohol; at 5 - 20 ℃; for 3.5h;
DOI:10.1016/S0040-4039(98)01823-1