3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

Base Information

Chemical Name:3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside
CAS No.:216871-53-3
Molecular Formula:C₃₇H₄₂O₆S
Molecular Weight:614.803
Hs Code.:

Synonyms:3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

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Technology Process of 3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

There total 3 articles about 3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 72174-24-4,53269-97-9
(2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-thiol

: 627-30-5
1-chloro-3-hydroxypropane

: 216871-53-3
3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

Guidance literature:: With potassium carbonate; In acetone; Heating;
DOI:10.1016/S0040-4039(98)01823-1

Reference yield:

: 72174-24-4,53269-97-9
(2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-thiol

: 627-18-9
1-bromo-3-propanol

: 216871-53-3
3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1021/jo400020q

Reference yield:

: 916453-28-6
2,3,4,6-tetra-O-benzyl-β-D-(4-monomethoxytrityl) thioglucoside

: 216871-53-3
3'-hydroxyprop-1'-yl 2,6-anhydro-2,3,4,6-tetra-O-benzyl-1-thio-βD-glucoside

Guidance literature:: Multi-step reaction with 2 steps

1: trifluoroacetic acid / dichloromethane / 1 h / Inert atmosphere

2: triethylamine / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere

With triethylamine; trifluoroacetic acid; In dichloromethane;
DOI:10.1021/jo400020q