(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene

Base Information

• Chemical Name: (4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene
• CAS No.: 112579-52-9
• Molecular Formula: C₁₆H₂₁BFeO₂
• Molecular Weight: 312
• Mol file: 112579-52-9.mol

Synonyms:(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene

Chemical Property of (4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene

There total 1 articles about (4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

ferrocene (102-54-5,55404-68-7) + bis(pinacol)diborane (73183-34-3) → (4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene (112579-52-9) + 1,1′-ferrocenediboronic acidbis(pinacol)ester (737776-93-1)

Guidance literature:

With catalyst:(IrOMe(cod))2/4,4'-di-tBu-2,2'-bipy; In octane; under Ar; (Ir(OMe)(cod))2 (0.015 mmol), 4,4'-di-tert-butyl-2,2'-bipyridine (0.03 mmol), bis(pinacolato)diboron (6.0 mmol) placed in Schlenk tube; octane and ferrocene (2.0 mmol) added; mixt. refluxed at 126°C for 24 h; column chromy. (silica gel, cyclohexane/ethyl acetate);

DOI:10.1039/b403419h

Reference yield: 55.0%

(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene (112579-52-9) + di(1-adamantyl)benzylphosphane (395116-70-8) → p-ferrocenylacetophenone

Guidance literature:

sodium tetrachloropalladate(II); In tetrahydrofuran; under Ar; 24 h, 65°C (Suzuki coupling);

DOI:10.1039/b403419h

Reference yield: 55.0%

N-iodo-succinimide (516-12-1) + (4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)ferrocene (112579-52-9) → iodoferrocene (1273-76-3)

Guidance literature:

In not given; under Ar; 4 h, room temp.;

DOI:10.1039/b403419h

upstream raw materials:

ferrocene

bis(pinacol)diborane

Downstream raw materials:

iodoferrocene

Refernces