methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside

Base Information

Chemical Name:methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside
CAS No.:150412-51-4
Molecular Formula:C₄₁H₄₄O₉S
Molecular Weight:712.861
Hs Code.:

Synonyms:methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside

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Technology Process of methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside

There total 6 articles about methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.9%

: 100-39-0
benzyl bromide

: 150412-50-3
methyl 4-O-(4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside

: 150412-51-4
methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside

Guidance literature:: With potassium hydroxide; In N,N-dimethyl-formamide; for 2h;
DOI:10.1016/0008-6215(93)80099-Z

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 150412-51-4
methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / p-toluenesulfonic acid / CH₂Cl₂ / 1 h

2: 75.9 percent / KOH / dimethylformamide / 2 h

With potassium hydroxide; toluene-4-sulfonic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(93)80099-Z

Reference yield:

: 30694-94-1
2,4,6-tri-O-acetate-3-O-methyl-α-D-glucopyranosylbromide

: 150412-51-4
methyl 4-O-(2-O-benzyl-4,6-O-benzylidene-3-O-methyl-β-D-glucopyranosyl)-2,3-O-diphenylmethylene-1-thio-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 77 percent / silver triflate, molecular sieves 4 Angstroem / CH₂Cl₂; toluene / 0.5 h / -40 °C

2: 96 percent / sodium methoxide / methanol

3: 83 percent / p-toluenesulfonic acid / CH₂Cl₂ / 1 h

4: 75.9 percent / KOH / dimethylformamide / 2 h

With potassium hydroxide; 4 A molecular sieve; sodium methylate; silver trifluoromethanesulfonate; toluene-4-sulfonic acid; In methanol; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1016/0008-6215(93)80099-Z